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- W3204383627 abstract "Abstract A molecular iodine catalyzed regioselective insertion of isocyanide into C2‐H of quinoline N ‐oxides has been developed. The reaction proceeds through the nucleophilic addition of isocyanide on quinoline N ‐oxides followed by rearrangement in presence of iodine. This metal‐free reaction affords rapid access to quinoline 2‐formamides with exceptional functional group tolerance, broad substrate scope and 100% atom‐economy. A library of 33 N ‐(2‐quinolinyl)formamides are synthesized, which may find applications in pharmaceuticals and synthetic chemistry. magnified image" @default.
- W3204383627 created "2021-10-11" @default.
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- W3204383627 date "2021-10-12" @default.
- W3204383627 modified "2023-10-16" @default.
- W3204383627 title "Iodine Catalyzed C2‐H Formamidation of Quinoline <i>N</i>‐Oxides using Isocyanides: A Metal‐Free Approach" @default.
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- W3204383627 doi "https://doi.org/10.1002/adsc.202100883" @default.
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