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- W3204394300 abstract "A study has been made of the reaction between powdered tin and organic chlorides, such as butyl chloride, benzyl chloride, p-methyl-benzyl chloride, diphenyl-methyl chloride and p-m-dimethyl-benzyl chloride in an ionizing radiation field. It is shown that while butyl chloride is heated to 200/sup 0/C in a gamma radiation field (dose rate of 300 r/s) for 40 hours, it does not react with tin. It is assumed that reduction of alkyl halides with a metal must be facilitated as the effective negative charge on the halide atom decreases. It has been established that benzyl chloride and substituted benzyl chlorides react in the absence of solvents at room temperature with a yield of 20 to 40%, the dose rate being 300 r/s. The reaction proceeds in two directions: formation of a tin-organic compound and dimerization. The ratio of the reaction products depends on the stability of the intermediate product of break-up of the C-Cl bond." @default.
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- W3204394300 date "1977-01-01" @default.
- W3204394300 modified "2023-09-27" @default.
- W3204394300 title "Tin interaction with organic chlorides in ionizing radiation field. [. gamma. rays]" @default.
- W3204394300 hasPublicationYear "1977" @default.
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