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- W3204402629 abstract "In this present work, NiOx nanoparticles were coated over cotton cloth for U6+ removal under various environmentally relevant conditions. Characterization of the NiOx-coated cotton cloth showed a nanoflower-structured morphology over the cotton fabric, with poly-crystalline α-3Ni(OH)2·2H2O and microcrystalline cellulose on the surface. XRF analysis of the cloth revealed the presence of 93% of Ni, while XPS analysis indicated that the Ni present on the cloth was in the form of Ni2+2p3/2 and Ni2+2p1/2. The NiOx-coated cotton cloth exhibited excellent U6+ immobilization with 93.5% removal within 6 min. The sorption capacity was ascertained to be 12.05 mg/g, and equilibrium studies indicated favorable monolayer adsorption. Solution pH had a significant effect on U6+ sorption on NiOx-coated cotton cloth, with maximum immobilization occurring at pH 6. Sorption kinetics was best explained using pseudo-second order kinetics indicating chemisorption-based process. Post-sorption XPS of U6+sorbed NiOx modified cotton cloth revealed only U6+ with no reduced forms, suggesting a pure adsorption-based immobilization mechanism. The superior performance even amongst the competing ions-demonstrated that the NiOx-coated cotton cloth is a low-cost, effective material for U6+ removal." @default.
- W3204402629 created "2021-10-11" @default.
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- W3204402629 date "2021-11-01" @default.
- W3204402629 modified "2023-10-12" @default.
- W3204402629 title "NiOx modified cellulose cloth for the removal of U(VI) from water" @default.
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- W3204402629 doi "https://doi.org/10.1016/j.apt.2021.09.039" @default.
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