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- W3204455053 abstract "Production of multicarbon (C2+) liquid fuels is a challenging task for electrocatalytic CO2 reduction, mainly limited by the stabilization of reaction intermediates and their subsequent C−C couplings. In this work, we report a unique catalyst, the coordinatively unsaturated Cu sites on amorphous CuTi alloy (a-CuTi@Cu) toward electrocatalytic CO2 reduction to multicarbon (C2-4) liquid fuels. Remarkably, the electrocatalyst yields ethanol, acetone, and n-butanol as major products with a total C2-4 faradaic efficiency of about 49 % at −0.8 V vs. reversible hydrogen electrode (RHE), which can be maintained for at least 3 months. Theoretical simulations and in situ characterization reveals that subsurface Ti atoms can increase the electron density of surface Cu sites and enhance the adsorption of *CO intermediate, which in turn reduces the energy barriers required for *CO dimerization and trimerization." @default.
- W3204455053 created "2021-10-11" @default.
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- W3204455053 date "2021-11-09" @default.
- W3204455053 modified "2023-10-11" @default.
- W3204455053 title "Ultrastable Cu Catalyst for CO <sub>2</sub> Electroreduction to Multicarbon Liquid Fuels by Tuning C–C Coupling with CuTi Subsurface" @default.
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- W3204455053 doi "https://doi.org/10.1002/anie.202110303" @default.
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