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- W3204534626 abstract "Abstract A novel protocol is accomplished for transformation of 2‐amino‐7,7‐dimethyl‐5‐ oxo ‐4‐phenyl‐5,6,7,8‐tetrahydro‐4 H ‐chromene‐3‐carbonitrile ( 1 ) into dihydrobenzofuran‐2,2‐dicarbonitriles ( 2 ) by reacting with N ‐chlorosuccinimide in presence of base at ambient temperature. On the other hand, same reaction with6‐amino‐3‐methyl‐1,4‐diphenyl‐1,4‐dihydropyrano[2,3‐ c ]pyrazole‐5‐carbonitrile ( 3 ) and NCS, surprisingly lead to formation of bispyrazolospirocyclopropanes ( 5 ). Simple reaction conditions, excellent yields and high compatibility are the advantages of this protocol." @default.
- W3204534626 created "2021-10-11" @default.
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- W3204534626 date "2021-10-01" @default.
- W3204534626 modified "2023-10-07" @default.
- W3204534626 title "Base‐Promoted Synthetic Transformation of 4<i>H</i>‐Chromenes into Dihydrobenzofurans and Bispyrazolospirocyclopropanes via Intramolecular Cyclization" @default.
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- W3204534626 doi "https://doi.org/10.1002/slct.202102655" @default.
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