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• W3204562180 abstract "Abstract In this work, an universal synthetic approach for the synthesis of D 2 ‐labeled nitrogen heterocycles based on cycloaddition reactions of in situ generated dideuteroacetylene is reported. A key feature of this method is the use of 1,4‐dioxane as a deuterium‐exchange‐proof solvent, which allowed the access to dideuterosubstituted heterocycles in up to 99 % deuteration degree. The method was demonstrated to be suitable for the synthesis of D 2 ‐labeled triazoles, isoxazoles, pyrazoles and pyridazines." @default.
• W3204562180 created "2021-10-11" @default.
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• W3204562180 date "2021-11-04" @default.
• W3204562180 modified "2023-10-17" @default.
• W3204562180 title "Cycloaddition Reactions of <i>in situ</i> Generated C ₂ D ₂ in Dioxane: Efficient Synthetic Approach to D ₂ ‐Labeled Nitrogen Heterocycles" @default.
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• W3204562180 doi "https://doi.org/10.1002/ejoc.202101085" @default.
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