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- W3204577694 abstract "Abstract Root chemicals and the sequences of the internal transcribed spacers (ITSs) were analyzed for 9 Ligularia kanaitzensis and 3 L. subspicata samples collected in northwestern Yunnan and southwestern Sichuan, China. Subspicatins A and C were isolated from two L. kanaitzensis samples. Introgression of genes responsible for these compounds from L. subspicata was suggested by their strong connection with L. subspicata / L. lamarum and the geographical proximity of the samples to L. subspicata . DNA analysis of a set of 27 L. kanaitzensis samples including those analyzed previously showed that they belong to two clades, designated A and B. Together with the presence/absence of furanoeremophilane, the 27 samples were sorted into three groups: clade A/furan, clade B/furan, and clade B/non‐furan. The ancestral plant presumably belonged to clade B/non‐furan, because furanoeremophilanes are biosynthesized from eremophilan‐8‐ones. 1β‐Angeloyloxyfukinone, a likely intermediate between fukinone and subspicatin C, was isolated for the first time. This finding allowed us to propose plausible biosynthetic pathways of subspicatins A and C." @default.
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- W3204577694 date "2021-10-20" @default.
- W3204577694 modified "2023-09-24" @default.
- W3204577694 title "Chemical and Genetic Diversity of <i>Ligularia kanaitzensis</i> in the Hengduan Mountains Area. Chemical Relationship with <i>L. subspicata</i>" @default.
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- W3204577694 doi "https://doi.org/10.1002/cbdv.202100444" @default.
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