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- W3204602457 abstract "The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies." @default.
- W3204602457 created "2021-10-11" @default.
- W3204602457 creator A5023058395 @default.
- W3204602457 creator A5030611363 @default.
- W3204602457 date "2020-06-01" @default.
- W3204602457 modified "2023-09-25" @default.
- W3204602457 title "Self-Assembly of a Chiral Cubic Three-Connected Net from the High Symmetry Molecules C60 and SnI4" @default.
- W3204602457 doi "https://doi.org/10.26434/chemrxiv.12196788.v2" @default.
- W3204602457 hasPublicationYear "2020" @default.
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