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- W3204641092 endingPage "13315" @default.
- W3204641092 startingPage "13307" @default.
- W3204641092 abstract "Although porous organic cages (POCs), particularly imine-linked (C[double bond, length as m-dash]N) ones, have advanced significantly over the last few decades, the reversible nature of imine linkages makes them prone to hydrolysis and structural collapse, severely limiting their applications under moist or water conditions. Herein, seven water-stable hydrazone-linked (C[double bond, length as m-dash]N-N) POCs are prepared through a simple coupling of the same supramolecular tetraformylresorcin[4]arene cavitand with different dihydrazide linkers. Their structures are all determined by single-crystal X-ray crystallography, demonstrating rich structural diversity from the [2 + 4] lantern, [3 + 6] triangular prism, and unprecedented [4 + 8] square prism to the extra-large [6 + 12] octahedron. In addition, they respectively exhibit tunable window diameters and cavity volumes ranging from about 5.4 to 11.1 nm and 580 to 6800 Å3. Moreover, their application in the water environment for pollutant removal was explored, indicating that they can effectively eliminate various types of contaminants from water, including radionuclide waste, toxic heavy metal ions, and organic micropollutants. This work demonstrates a convenient method for rationally constructing versatile robust POCs and presents their great application potentialities in water medium." @default.
- W3204641092 created "2021-10-11" @default.
- W3204641092 creator A5012826703 @default.
- W3204641092 creator A5014194104 @default.
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- W3204641092 creator A5032418200 @default.
- W3204641092 creator A5035390879 @default.
- W3204641092 creator A5067399188 @default.
- W3204641092 date "2021-01-01" @default.
- W3204641092 modified "2023-10-14" @default.
- W3204641092 title "Water-stable hydrazone-linked porous organic cages" @default.
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