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- W3204649797 abstract "A concise synthesis of the tricyclic guanidinium alkaloid batzelladine D has been accomplished in a sequence of 8 steps from readily available building blocks. Highlights of the synthesis include gram-scale preparation of a late stage intermediate, pinpoint stereocontrol around the tricyclic skeleton and a modular strategy that enables analog generation. A key bicyclic b-lactam intermediate serves to not only control stereochemistry, but also serves as a pre-activated coupling partner to install the ester sidechain. The stereo-controlled synthesis allowed for the investigation of the antimicrobial activity of batzelladine D, demonstrating promising activity that is more potent for non-natural stereoisomers." @default.
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- W3204649797 date "2019-10-03" @default.
- W3204649797 modified "2023-09-27" @default.
- W3204649797 title "Concise Synthesis and Antimicrobial Evaluation of the Guanidinium Alkaloid Batzelladine D" @default.
- W3204649797 cites W2164641603 @default.
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- W3204649797 doi "https://doi.org/10.26434/chemrxiv.9924692.v1" @default.
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