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- W3204650776 endingPage "113565" @default.
- W3204650776 startingPage "113565" @default.
- W3204650776 abstract "Herein, a monomeric copper(II) complex of the general formula [Cu(L)Cl2] (1) and a polymeric copper(II) complex bearing the formula [Cu2L/2(µ-N3)(N3)]n, (2) have been synthesized using NNN and NNO tridentate Schiff base ligands, L and L/ where L = N-((6-methoxypyridin-2-yl)methylene)(piperidin-2-yl)methane amine and L/ = 1-((3-(methylamino)propylimino)methyl)naphthalene-2-ol. Both the complexes have been characterized by single crystal X-ray diffraction and UV–Vis, FTIR, ESI-MS spectroscopic studies. The crystal structure of the complex (1) reveals a square pyramidal geometry whereas the structure of the complex (2) exhibits elongated square pyramidal geometry and the asymmetric unit of the complex contains two Cu(II) ions connected by the single µ-azido bridge. The electronic structures of the complexes are optimized by Density Functional Theory (DFT) calculations to explore their coordination stabilities and chemically reactive parameters. Besides, the Hirshfeld surfaces and two-dimensional fingerprint plot are also carried out to visualize the intermolecular interactions in the crystal of complex 1 and complex 2. Photodegradation against Methylene Blue (MB) proves the greater efficiency of complex 2 as a photodegradation agent for MB organic pollutant dye. Preferential binding studies of both the complexes towards the protein, Bovine Serum Albumin (BSA), by a series of spectroscopic techniques reveal that complex 1 strongly interacts with BSA. The spectroscopic data are well correlated by molecular docking studies. These interaction studies prompted us for cell viability studies against SiHa cancer cell to check whether the complexes may be used as biomaterial transplants or not. It is observed that the cell viability increases with time demonstrating the biocompatible nature of the complexes as well as their uses as biomaterial transplants." @default.
- W3204650776 created "2021-10-11" @default.
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- W3204650776 date "2022-01-01" @default.
- W3204650776 modified "2023-10-01" @default.
- W3204650776 title "Copper(II) complexes with NNN and NNO Schiff base ligands as efficient photodegradation agents for methylene blue, preferential BSA binder and biomaterial transplants" @default.
- W3204650776 cites W1734517644 @default.
- W3204650776 cites W1873958974 @default.
- W3204650776 cites W1905183855 @default.
- W3204650776 cites W1964932856 @default.
- W3204650776 cites W1969360633 @default.
- W3204650776 cites W1969635440 @default.
- W3204650776 cites W1975797915 @default.
- W3204650776 cites W1978345586 @default.
- W3204650776 cites W1978633893 @default.
- W3204650776 cites W1984249618 @default.
- W3204650776 cites W1984883623 @default.
- W3204650776 cites W1986747402 @default.
- W3204650776 cites W1990170643 @default.
- W3204650776 cites W1993127104 @default.
- W3204650776 cites W1995917254 @default.
- W3204650776 cites W1997059729 @default.
- W3204650776 cites W2006829240 @default.
- W3204650776 cites W2012488984 @default.
- W3204650776 cites W2013176211 @default.
- W3204650776 cites W2014286678 @default.
- W3204650776 cites W2016064019 @default.
- W3204650776 cites W2021388388 @default.
- W3204650776 cites W2035162565 @default.
- W3204650776 cites W2037920515 @default.
- W3204650776 cites W2044966953 @default.
- W3204650776 cites W2049987247 @default.
- W3204650776 cites W2053106379 @default.
- W3204650776 cites W2053227378 @default.
- W3204650776 cites W2057977480 @default.
- W3204650776 cites W2062532800 @default.
- W3204650776 cites W2063084254 @default.
- W3204650776 cites W2074311427 @default.
- W3204650776 cites W2076454765 @default.
- W3204650776 cites W2084286681 @default.
- W3204650776 cites W2098362109 @default.
- W3204650776 cites W2100643813 @default.
- W3204650776 cites W2101982331 @default.
- W3204650776 cites W2111627462 @default.
- W3204650776 cites W2113272836 @default.
- W3204650776 cites W2126462258 @default.
- W3204650776 cites W2143264835 @default.
- W3204650776 cites W2158534713 @default.
- W3204650776 cites W2161986640 @default.
- W3204650776 cites W2170309222 @default.
- W3204650776 cites W2200938472 @default.
- W3204650776 cites W2298892810 @default.
- W3204650776 cites W2312599638 @default.
- W3204650776 cites W2313912827 @default.
- W3204650776 cites W2323249281 @default.
- W3204650776 cites W2332404794 @default.
- W3204650776 cites W2338830797 @default.
- W3204650776 cites W2440857570 @default.
- W3204650776 cites W2548046185 @default.
- W3204650776 cites W2804157377 @default.
- W3204650776 cites W2809880805 @default.
- W3204650776 cites W2888400067 @default.
- W3204650776 cites W2902081228 @default.
- W3204650776 cites W2904760835 @default.
- W3204650776 cites W2914798666 @default.
- W3204650776 cites W2945204071 @default.
- W3204650776 cites W2959853409 @default.
- W3204650776 cites W2969919748 @default.
- W3204650776 cites W2971502080 @default.
- W3204650776 cites W2992415500 @default.
- W3204650776 cites W3002047014 @default.
- W3204650776 cites W3017377913 @default.
- W3204650776 cites W3040543285 @default.
- W3204650776 cites W3092498173 @default.
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- W3204650776 doi "https://doi.org/10.1016/j.jphotochem.2021.113565" @default.
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