Matches in SemOpenAlex for { <https://semopenalex.org/work/W3204672826> ?p ?o ?g. }
- W3204672826 endingPage "1235" @default.
- W3204672826 startingPage "1229" @default.
- W3204672826 abstract "We construct a segmental scale force level theory for the center-of-mass diffusion constant and corresponding relaxation time for globally compact unconcatenated ring polymer solutions and melts (degree of polymerization N). The approach is based on slowly decaying macromolecular scale intermolecular force dynamic correlations as the origin of their unusual dynamics. Unentangled Rouse, weakly caged, and activated regimes are predicted. The barrier of the activated regime scales linearly with N and as a power law of concentration, which drives a kinetic glass transition on the radius-of-gyration scale. The values of N at the two dynamic crossovers (Rouse to weakly caged, weakly caged to activated) are proportional, with nonuniversality entering mainly via macromolecular volume fraction and dimensionless compressibility. Quantitative comparisons with simulation data reveal good agreement. Aspects of intermediate time dynamics are analyzed, and predictions are made for the conditions required to observe a macromolecular glass transition in the laboratory and on the computer." @default.
- W3204672826 created "2021-10-11" @default.
- W3204672826 creator A5036831657 @default.
- W3204672826 creator A5045572539 @default.
- W3204672826 creator A5056365326 @default.
- W3204672826 date "2021-09-24" @default.
- W3204672826 modified "2023-09-25" @default.
- W3204672826 title "Theory of Transient Localization, Activated Dynamics, and a Macromolecular Glass Transition in Ring Polymer Liquids" @default.
- W3204672826 cites W1502175635 @default.
- W3204672826 cites W1758167429 @default.
- W3204672826 cites W1969492208 @default.
- W3204672826 cites W1970970834 @default.
- W3204672826 cites W1971249019 @default.
- W3204672826 cites W1977209904 @default.
- W3204672826 cites W1987565940 @default.
- W3204672826 cites W1998259135 @default.
- W3204672826 cites W2001509772 @default.
- W3204672826 cites W2002688780 @default.
- W3204672826 cites W2007001643 @default.
- W3204672826 cites W2022728867 @default.
- W3204672826 cites W2023169683 @default.
- W3204672826 cites W2028457175 @default.
- W3204672826 cites W2045115146 @default.
- W3204672826 cites W2064888668 @default.
- W3204672826 cites W2069785532 @default.
- W3204672826 cites W2074707035 @default.
- W3204672826 cites W2081641111 @default.
- W3204672826 cites W2088667438 @default.
- W3204672826 cites W2128868875 @default.
- W3204672826 cites W2145662774 @default.
- W3204672826 cites W2230648959 @default.
- W3204672826 cites W2314503669 @default.
- W3204672826 cites W2414118476 @default.
- W3204672826 cites W2415884520 @default.
- W3204672826 cites W2480068994 @default.
- W3204672826 cites W2503517549 @default.
- W3204672826 cites W2599703488 @default.
- W3204672826 cites W2608438661 @default.
- W3204672826 cites W2885768200 @default.
- W3204672826 cites W2899867357 @default.
- W3204672826 cites W2946033120 @default.
- W3204672826 cites W2949140630 @default.
- W3204672826 cites W2997921545 @default.
- W3204672826 cites W3000230211 @default.
- W3204672826 cites W3037336493 @default.
- W3204672826 cites W3040280630 @default.
- W3204672826 cites W3042023459 @default.
- W3204672826 cites W3102858933 @default.
- W3204672826 cites W3103660708 @default.
- W3204672826 cites W3105701304 @default.
- W3204672826 cites W3106186262 @default.
- W3204672826 cites W3176512167 @default.
- W3204672826 cites W33359099 @default.
- W3204672826 doi "https://doi.org/10.1021/acsmacrolett.1c00530" @default.
- W3204672826 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35549053" @default.
- W3204672826 hasPublicationYear "2021" @default.
- W3204672826 type Work @default.
- W3204672826 sameAs 3204672826 @default.
- W3204672826 citedByCount "4" @default.
- W3204672826 countsByYear W32046728262021 @default.
- W3204672826 countsByYear W32046728262022 @default.
- W3204672826 countsByYear W32046728262023 @default.
- W3204672826 crossrefType "journal-article" @default.
- W3204672826 hasAuthorship W3204672826A5036831657 @default.
- W3204672826 hasAuthorship W3204672826A5045572539 @default.
- W3204672826 hasAuthorship W3204672826A5056365326 @default.
- W3204672826 hasConcept C121332964 @default.
- W3204672826 hasConcept C122865956 @default.
- W3204672826 hasConcept C15744967 @default.
- W3204672826 hasConcept C159467904 @default.
- W3204672826 hasConcept C159985019 @default.
- W3204672826 hasConcept C166950319 @default.
- W3204672826 hasConcept C168568712 @default.
- W3204672826 hasConcept C178790620 @default.
- W3204672826 hasConcept C185592680 @default.
- W3204672826 hasConcept C191516044 @default.
- W3204672826 hasConcept C192562407 @default.
- W3204672826 hasConcept C204389451 @default.
- W3204672826 hasConcept C24872484 @default.
- W3204672826 hasConcept C2776029896 @default.
- W3204672826 hasConcept C32909587 @default.
- W3204672826 hasConcept C44228677 @default.
- W3204672826 hasConcept C521977710 @default.
- W3204672826 hasConcept C55493867 @default.
- W3204672826 hasConcept C69357855 @default.
- W3204672826 hasConcept C77805123 @default.
- W3204672826 hasConcept C97355855 @default.
- W3204672826 hasConceptScore W3204672826C121332964 @default.
- W3204672826 hasConceptScore W3204672826C122865956 @default.
- W3204672826 hasConceptScore W3204672826C15744967 @default.
- W3204672826 hasConceptScore W3204672826C159467904 @default.
- W3204672826 hasConceptScore W3204672826C159985019 @default.
- W3204672826 hasConceptScore W3204672826C166950319 @default.
- W3204672826 hasConceptScore W3204672826C168568712 @default.
- W3204672826 hasConceptScore W3204672826C178790620 @default.
- W3204672826 hasConceptScore W3204672826C185592680 @default.
- W3204672826 hasConceptScore W3204672826C191516044 @default.
- W3204672826 hasConceptScore W3204672826C192562407 @default.