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- W3204677922 abstract "A novel methodology to access synthetically versatile vinylboronic esters through a ligand-controlled cobalt-catalyzed hydroboration of terminal and internal alkynes is reported. The approach relies on the in situ reduction of Co(II) by H-BPin in the presence of bisphosphine ligands generating catalytically active Co(I) hydride complexes. This procedure avoids the use of stoichiometric amounts of base, and no boron-containing byproducts are generated which is translated into high functional group tolerance and atom economy." @default.
- W3204677922 created "2021-10-11" @default.
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- W3204677922 date "2021-10-07" @default.
- W3204677922 modified "2023-10-18" @default.
- W3204677922 title "Cobalt-Catalyzed Hydroboration of Terminal and Internal Alkynes" @default.
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- W3204677922 doi "https://doi.org/10.1021/acs.orglett.1c02854" @default.
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