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- W3204687812 abstract "Layered 2D (PbI2 )1-x (BiI3 )x materials exhibit a nonlinear dependence in structural and charge transport properties unanticipated from the combination of PbI2 and BiI3 . Within (PbI2 )1-x (BiI3 )x crystals, phase integration yields deceptive structural features, while phase boundary separation leads to new conductance switching behavior observed as large peaks in current during current-voltage (I-V) measurements (±100 V). Temperature- and time-dependent electrical measurements demonstrate that the behavior is attributed to ionic transport perpendicular to the layers. High-resolution transmission electron microscopy reveals that the structure of (PbI2 )1-x (BiI3 )x is a brick wall consisting of two phases, Pb-rich and Bi-rich. These brick-like features are 10s nm a side and it is posited that iodide ion transport at the interfaces of these regions is responsible for the conductance switching action." @default.
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- W3204687812 date "2021-10-15" @default.
- W3204687812 modified "2023-10-16" @default.
- W3204687812 title "Controllable Nonclassical Conductance Switching in Nanoscale Phase‐Separated (PbI 2 ) 1− x (BiI 3 ) x Layered Crystals" @default.
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- W3204687812 doi "https://doi.org/10.1002/adma.202103098" @default.
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