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- W3204693347 abstract "The molecular electric field gradient (e qzz)₆₁₀ at the nucleus of the gold isotope 197 is 42,7 · 10¹⁵ esu cm⁻³ according to our calculations. This value was used in calculating the quadrupole coupling constant in AuI and agreement is found with the experimental quadrupole coupling constant (e² Q qzz)/h=508.296 MHz, if 50% s²-hybridisation and 21% ionicity are attributed to the gold-iodine bond. The ionicity in AuI is perhaps greater than in AuCl, as is indicated by the lower quadrupole coupling constant of Au¹⁹⁷ in Aul.((e² Q qzz) /h=508,296 MHz in AuI, 514,150 MHz in AuCl ¹.) This result is discussed with respect to the Townes-Dailey rule" @default.
- W3204693347 created "2021-10-11" @default.
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- W3204693347 date "2014-01-01" @default.
- W3204693347 modified "2023-09-23" @default.
- W3204693347 title "About the chemical bond in gold (i)-iodide" @default.
- W3204693347 hasPublicationYear "2014" @default.
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