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- W3204809721 abstract "Cobalt-catalyzed regioselective three-component arylcarboxylation of acrylate with aryl bromides and carbon dioxide has been developed. The reaction is carried out by using cobalt chloride as a precatalyst and zinc powder as a reducing reagent under CO2 (1 atm) at 40 °C. A range of aryl bromides are used for this reaction, leading to a series of valuable carboxylic acids with high regioselectivity and functional-group compatibility. Mechanistic experiments and DFT calculations indicate that this arylcarboxylation reaction involves the reaction of CO2 with a cobalt enolate intermediate to form the C-C bond." @default.
- W3204809721 created "2021-10-11" @default.
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- W3204809721 date "2021-10-27" @default.
- W3204809721 modified "2023-10-18" @default.
- W3204809721 title "Cobalt‐Catalyzed Highly Regioselective Three‐Component Arylcarboxylation of Acrylate with Aryl Bromides and Carbon Dioxide" @default.
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- W3204809721 doi "https://doi.org/10.1002/cssc.202101963" @default.
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