Matches in SemOpenAlex for { <https://semopenalex.org/work/W3205024300> ?p ?o ?g. }
- W3205024300 endingPage "2103375" @default.
- W3205024300 startingPage "2103375" @default.
- W3205024300 abstract "Lithium metal is a promising anode material for lithium metal batteries (LMBs). However, dendrite growth and limited Coulombic efficiency (CE) during cycling have prevented its practical application in rechargeable batteries. Herein, a highly concentrated electrolyte composed of an ether solvent and lithium bis(fluorosulfonyl)imide (LiFSI) salt is introduced, which enables the cycling of a lithium metal anode at a high CE (up to ≈99%) without dendrite growth, even at high current densities. Using 3.85 m LiFSI in tetrahydrofuran (THF) as the electrolyte, a Li||Li symmetric cell can be cycled at 1.0 mA cm−2 for more than 1000 h with stable polarization of ≈0.1 V, and Li||LFP cells can be cycled at 2 C (1 C = 170 mA g−1) for more than 1000 cycles with a capacity retention of 94.5%. These excellent performances are observed to be attributed to the increased cation–anion associated complexes, such as contact ion pairs and aggregate in the highly concentrated electrolyte; revealed by Raman spectroscopy and theoretical calculations. These results demonstrate the benefits of a high-concentration LiFSI–THF electrolyte system, generating new possibilities for high-energy-density rechargeable LMBs." @default.
- W3205024300 created "2021-10-25" @default.
- W3205024300 creator A5002297059 @default.
- W3205024300 creator A5044653228 @default.
- W3205024300 creator A5063078837 @default.
- W3205024300 date "2021-10-11" @default.
- W3205024300 modified "2023-10-01" @default.
- W3205024300 title "Design of a LiF‐Rich Solid Electrolyte Interphase Layer through Highly Concentrated LiFSI–THF Electrolyte for Stable Lithium Metal Batteries" @default.
- W3205024300 cites W1971271131 @default.
- W3205024300 cites W1972767018 @default.
- W3205024300 cites W1985875339 @default.
- W3205024300 cites W1990410734 @default.
- W3205024300 cites W1997050880 @default.
- W3205024300 cites W2028456770 @default.
- W3205024300 cites W2047775546 @default.
- W3205024300 cites W2053151965 @default.
- W3205024300 cites W2061039743 @default.
- W3205024300 cites W2064944515 @default.
- W3205024300 cites W2066015753 @default.
- W3205024300 cites W2070416274 @default.
- W3205024300 cites W2079776700 @default.
- W3205024300 cites W2089403233 @default.
- W3205024300 cites W2093414302 @default.
- W3205024300 cites W2124552702 @default.
- W3205024300 cites W2153095586 @default.
- W3205024300 cites W2155489103 @default.
- W3205024300 cites W2169211003 @default.
- W3205024300 cites W2229626598 @default.
- W3205024300 cites W2263500971 @default.
- W3205024300 cites W2285230820 @default.
- W3205024300 cites W2288134521 @default.
- W3205024300 cites W2408156250 @default.
- W3205024300 cites W2469089667 @default.
- W3205024300 cites W2527729130 @default.
- W3205024300 cites W2594331606 @default.
- W3205024300 cites W2602657889 @default.
- W3205024300 cites W2622680715 @default.
- W3205024300 cites W2763902109 @default.
- W3205024300 cites W2765147628 @default.
- W3205024300 cites W2774731903 @default.
- W3205024300 cites W2799788550 @default.
- W3205024300 cites W2800771806 @default.
- W3205024300 cites W2808438592 @default.
- W3205024300 cites W2810854392 @default.
- W3205024300 cites W2811444372 @default.
- W3205024300 cites W2885891447 @default.
- W3205024300 cites W2905391333 @default.
- W3205024300 cites W2905549234 @default.
- W3205024300 cites W2911391961 @default.
- W3205024300 cites W2921954478 @default.
- W3205024300 cites W2922443589 @default.
- W3205024300 cites W2924964892 @default.
- W3205024300 cites W2939011960 @default.
- W3205024300 cites W2947261675 @default.
- W3205024300 cites W2949049758 @default.
- W3205024300 cites W2982150954 @default.
- W3205024300 cites W2991045665 @default.
- W3205024300 cites W2994377960 @default.
- W3205024300 cites W2996331339 @default.
- W3205024300 cites W2997649224 @default.
- W3205024300 cites W3001852058 @default.
- W3205024300 cites W3016996355 @default.
- W3205024300 cites W3025473585 @default.
- W3205024300 cites W3035811909 @default.
- W3205024300 cites W3096189196 @default.
- W3205024300 cites W3128637898 @default.
- W3205024300 cites W3148917090 @default.
- W3205024300 doi "https://doi.org/10.1002/smll.202103375" @default.
- W3205024300 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34636172" @default.
- W3205024300 hasPublicationYear "2021" @default.
- W3205024300 type Work @default.
- W3205024300 sameAs 3205024300 @default.
- W3205024300 citedByCount "30" @default.
- W3205024300 countsByYear W32050243002021 @default.
- W3205024300 countsByYear W32050243002022 @default.
- W3205024300 countsByYear W32050243002023 @default.
- W3205024300 crossrefType "journal-article" @default.
- W3205024300 hasAuthorship W3205024300A5002297059 @default.
- W3205024300 hasAuthorship W3205024300A5044653228 @default.
- W3205024300 hasAuthorship W3205024300A5063078837 @default.
- W3205024300 hasConcept C127413603 @default.
- W3205024300 hasConcept C130349721 @default.
- W3205024300 hasConcept C134018914 @default.
- W3205024300 hasConcept C147789679 @default.
- W3205024300 hasConcept C17525397 @default.
- W3205024300 hasConcept C178790620 @default.
- W3205024300 hasConcept C179104552 @default.
- W3205024300 hasConcept C185592680 @default.
- W3205024300 hasConcept C191897082 @default.
- W3205024300 hasConcept C192562407 @default.
- W3205024300 hasConcept C205049153 @default.
- W3205024300 hasConcept C2778541603 @default.
- W3205024300 hasConcept C2780471494 @default.
- W3205024300 hasConcept C2994426979 @default.
- W3205024300 hasConcept C42360764 @default.
- W3205024300 hasConcept C544153396 @default.
- W3205024300 hasConcept C68801617 @default.
- W3205024300 hasConcept C71924100 @default.