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• W3205374379 abstract "The nucleophilic addition of ketene silyl acetals 2 into 2H-azirines 1 proceeded in the presence of Lewis acids such as InX3 or Sc(OTf)3 to give N-unprotected aziridines 3. The mild Lewis acidity of the catalyst is important for the achievement of this coupling. The generated aziridine 3 could then be transformed into either oxazolines or γ–amino carbonyls. N-unprotected aziridines were obtained via coupling of 2H-azirines with ketene silyl acetals in the presence of Lewis acids such as InX3 or Sc(OTf)3. Mild Lewis acidity was key to achieve the coupling. The generated aziridines were converted into γ-amino carbonyl compounds or an oxazoline ring." @default.
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• W3205374379 date "2022-01-05" @default.
• W3205374379 modified "2023-09-27" @default.
• W3205374379 title "One-step Preparation of N-Unprotected Aziridines from 2<i>H</i>-Azirines by Addition of Ketene Silyl Acetals Catalyzed by Lewis Acids" @default.
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• W3205374379 doi "https://doi.org/10.1246/cl.210589" @default.
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