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• W3205401023 endingPage "132532" @default.
• W3205401023 startingPage "132532" @default.
• W3205401023 abstract "Biocatalytically synthesized mono-rhamnolipids are eco-friendly surfactants that exhibit strong industrial applications owing to their low toxicity and biodegradability as well as their efficient antimicrobial and surface tension reduction potential. In this present study, novel adsorbent chitosan encapsulated magnetic nanoparticles coated with rhamnolipids (Rh-cMNP) were prepared and used for the adsorption of the micropollutant acetaminophen. The SEM, FTIR, and VSM results showed that Rh-cMNP had abundant functional groups with a mesoporous feature and easy separation of the magnetic nanosorbent from the reaction mixture. The obtained nanosorbent was effectively used to remove acetaminophen, one of the most common persistent pharmaceutical pollutants in the environment. Optimization studies revealed the maximum removal of 96.7% acetaminophen with the ability of adsorption to be 96.3 mg/g at 60 min of contact time and process parameters of pH 5.0 and 303 K temperature. Langmuir isotherm was most favourable for the optimized data; kinetic studies obeyed pseudo-second-order whose feasibility and thermodynamic studies obtained spontaneity. Regeneration of used Rh-cMNP is performed with 0.1 N HCl/NaOH and observed to be consistent for eight adsorption-desorption cycles." @default.
• W3205401023 created "2021-10-25" @default.
• W3205401023 creator A5026512308 @default.
• W3205401023 creator A5058387151 @default.
• W3205401023 creator A5087935450 @default.
• W3205401023 date "2022-02-01" @default.
• W3205401023 modified "2023-09-29" @default.
• W3205401023 title "Synthesis and characterization of rhamnolipid based chitosan magnetic nanosorbents for the removal of acetaminophen from aqueous solution" @default.
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• W3205401023 doi "https://doi.org/10.1016/j.chemosphere.2021.132532" @default.
• W3205401023 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34648781" @default.
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