FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3205499008> ?p ?o ?g. }

• W3205499008 endingPage "127705" @default.
• W3205499008 startingPage "127705" @default.
• W3205499008 abstract "Poly(4-vinylpyridine) particles, P4VP, show a great potential from the environmental and economic perspective since they are cheap and extensively used for safer and greener organic syntheses. Moreover, their pH-sensitive properties would make it easy to obtain “on-off”, recyclable and reusable Pickering emulsions. The relationships between particle structures (size, shape, acidity and charge) and emulsion properties (type, droplet size and stability against environmental stresses) were investigated. The protonation increased the particles diameter to 147 nm compared to the pristine ones (88 nm) due to electrostatic repulsions which swell the particles. The ζ-potential was decreased with increasing acidity (from +60 to +30 mV) due to the accumulation of chlorides onto the surface. Thus, the acidic particles of 39 mmolH+/g and +57 mV were more effective in emulsifying heptane in water with long-term stability in storage conditions (up to one year) and unprecedented resistance against centrifugation and temperature (up to 5000 rpm and 60 °C). Nevertheless, destabilization can be easily achieved by pH or ionic strength changes facilitating the phase separation and the particles recovery. Contrary to the literature of responsive Pickering emulsions, which require relatively complex systems, the investigated one provides a simple route to obtain various “on-off” switches using P4VP cross-linked particles which possess changeable structures based on electrostatic repulsions. Consequently, the exploitation of such a system could be attractive in biphasic media in which the P4VP would act as a reagent, scavenger, and/or catalyst." @default.
• W3205499008 created "2021-10-25" @default.
• W3205499008 creator A5028298352 @default.
• W3205499008 creator A5039978382 @default.
• W3205499008 creator A5061065311 @default.
• W3205499008 date "2021-12-01" @default.
• W3205499008 modified "2023-09-23" @default.
• W3205499008 title "Cross-linked poly(4‐vinylpyridine) particles for pH- and ionic strength-responsive “on–off” Pickering emulsions" @default.
• W3205499008 cites W1975117973 @default.
• W3205499008 cites W2004505287 @default.
• W3205499008 cites W2004599923 @default.
• W3205499008 cites W2012116646 @default.
• W3205499008 cites W2017194099 @default.
• W3205499008 cites W2020352364 @default.
• W3205499008 cites W2027729210 @default.
• W3205499008 cites W2035389072 @default.
• W3205499008 cites W2043184909 @default.
• W3205499008 cites W2048571562 @default.
• W3205499008 cites W2056311049 @default.
• W3205499008 cites W2061153604 @default.
• W3205499008 cites W2064068449 @default.
• W3205499008 cites W2064605368 @default.
• W3205499008 cites W2071650674 @default.
• W3205499008 cites W2093124108 @default.
• W3205499008 cites W2121535639 @default.
• W3205499008 cites W2187073345 @default.
• W3205499008 cites W2329357680 @default.
• W3205499008 cites W2561683707 @default.
• W3205499008 cites W2617634995 @default.
• W3205499008 cites W2766733956 @default.
• W3205499008 cites W2800652188 @default.
• W3205499008 cites W2845219594 @default.
• W3205499008 cites W2896335231 @default.
• W3205499008 cites W2900875632 @default.
• W3205499008 cites W2912618570 @default.
• W3205499008 cites W2924000195 @default.
• W3205499008 cites W2943018199 @default.
• W3205499008 cites W2956840577 @default.
• W3205499008 cites W2970860203 @default.
• W3205499008 cites W2989813605 @default.
• W3205499008 cites W3015921453 @default.
• W3205499008 cites W3022761044 @default.
• W3205499008 cites W3041730832 @default.
• W3205499008 cites W3048393894 @default.
• W3205499008 cites W3092631753 @default.
• W3205499008 cites W3117398826 @default.
• W3205499008 cites W3119218823 @default.
• W3205499008 cites W3123572537 @default.
• W3205499008 cites W3139284970 @default.
• W3205499008 cites W3157979366 @default.
• W3205499008 cites W3166467040 @default.
• W3205499008 cites W873624173 @default.
• W3205499008 doi "https://doi.org/10.1016/j.colsurfa.2021.127705" @default.
• W3205499008 hasPublicationYear "2021" @default.
• W3205499008 type Work @default.
• W3205499008 sameAs 3205499008 @default.
• W3205499008 citedByCount "4" @default.
• W3205499008 countsByYear W32054990082022 @default.
• W3205499008 countsByYear W32054990082023 @default.
• W3205499008 crossrefType "journal-article" @default.
• W3205499008 hasAuthorship W3205499008A5028298352 @default.
• W3205499008 hasAuthorship W3205499008A5039978382 @default.
• W3205499008 hasAuthorship W3205499008A5061065311 @default.
• W3205499008 hasBestOaLocation W32054990081 @default.
• W3205499008 hasConcept C105341887 @default.
• W3205499008 hasConcept C111368507 @default.
• W3205499008 hasConcept C127313418 @default.
• W3205499008 hasConcept C127413603 @default.
• W3205499008 hasConcept C145148216 @default.
• W3205499008 hasConcept C155672457 @default.
• W3205499008 hasConcept C171250308 @default.
• W3205499008 hasConcept C178790620 @default.
• W3205499008 hasConcept C184651966 @default.
• W3205499008 hasConcept C185592680 @default.
• W3205499008 hasConcept C187428577 @default.
• W3205499008 hasConcept C187530423 @default.
• W3205499008 hasConcept C192562407 @default.
• W3205499008 hasConcept C202444582 @default.
• W3205499008 hasConcept C2778123984 @default.
• W3205499008 hasConcept C2778517922 @default.
• W3205499008 hasConcept C30095370 @default.
• W3205499008 hasConcept C33923547 @default.
• W3205499008 hasConcept C40875361 @default.
• W3205499008 hasConcept C42360764 @default.
• W3205499008 hasConcept C44280652 @default.
• W3205499008 hasConcept C5961521 @default.
• W3205499008 hasConcept C9271920 @default.
• W3205499008 hasConceptScore W3205499008C105341887 @default.
• W3205499008 hasConceptScore W3205499008C111368507 @default.
• W3205499008 hasConceptScore W3205499008C127313418 @default.
• W3205499008 hasConceptScore W3205499008C127413603 @default.
• W3205499008 hasConceptScore W3205499008C145148216 @default.
• W3205499008 hasConceptScore W3205499008C155672457 @default.
• W3205499008 hasConceptScore W3205499008C171250308 @default.
• W3205499008 hasConceptScore W3205499008C178790620 @default.
• W3205499008 hasConceptScore W3205499008C184651966 @default.
• W3205499008 hasConceptScore W3205499008C185592680 @default.
• W3205499008 hasConceptScore W3205499008C187428577 @default.

• next