FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3205584147> ?p ?o ?g. }

• W3205584147 endingPage "16561" @default.
• W3205584147 startingPage "16552" @default.
• W3205584147 abstract "The advent of on-surface chemistry under vacuum has vastly increased our capabilities to synthesize carbon nanomaterials with atomic precision. Among the types of target structures that have been synthesized by these means, graphene nanoribbons (GNRs) have probably attracted the most attention. In this context, the vast majority of GNRs have been synthesized from the same chemical reaction: Ullmann coupling followed by cyclodehydrogenation. Here, we provide a detailed study of the growth process of five-atom-wide armchair GNRs starting from dibromoperylene. Combining scanning probe microscopy with temperature-dependent XPS measurements and theoretical calculations, we show that the GNR growth departs from the conventional reaction scenario. Instead, precursor molecules couple by means of a concerted mechanism whereby two covalent bonds are formed simultaneously, along with a concomitant dehydrogenation. Indeed, this alternative reaction path is responsible for the straight GNR growth in spite of the initial mixture of reactant isomers with irregular metal-organic intermediates that we find. The provided insight will not only help understanding the reaction mechanisms of other reactants but also serve as a guide for the design of other precursor molecules." @default.
• W3205584147 created "2021-10-25" @default.
• W3205584147 creator A5002229288 @default.
• W3205584147 creator A5005749804 @default.
• W3205584147 creator A5008948855 @default.
• W3205584147 creator A5013678020 @default.
• W3205584147 creator A5021066913 @default.
• W3205584147 creator A5073782691 @default.
• W3205584147 creator A5079168781 @default.
• W3205584147 creator A5086689121 @default.
• W3205584147 creator A5091403848 @default.
• W3205584147 date "2021-10-11" @default.
• W3205584147 modified "2023-10-15" @default.
• W3205584147 title "Order from a Mess: The Growth of 5-Armchair Graphene Nanoribbons" @default.
• W3205584147 cites W1204378431 @default.
• W3205584147 cites W1560430361 @default.
• W3205584147 cites W1964565139 @default.
• W3205584147 cites W1965510235 @default.
• W3205584147 cites W1967445304 @default.
• W3205584147 cites W1975639388 @default.
• W3205584147 cites W1983208835 @default.
• W3205584147 cites W1983784909 @default.
• W3205584147 cites W1986055204 @default.
• W3205584147 cites W1991384072 @default.
• W3205584147 cites W1993154769 @default.
• W3205584147 cites W2001305258 @default.
• W3205584147 cites W2015630805 @default.
• W3205584147 cites W2021123019 @default.
• W3205584147 cites W2023271753 @default.
• W3205584147 cites W2025157404 @default.
• W3205584147 cites W2027683710 @default.
• W3205584147 cites W2029108965 @default.
• W3205584147 cites W2037504287 @default.
• W3205584147 cites W2051001465 @default.
• W3205584147 cites W2058595066 @default.
• W3205584147 cites W2092142891 @default.
• W3205584147 cites W2103562499 @default.
• W3205584147 cites W2140372631 @default.
• W3205584147 cites W2143981217 @default.
• W3205584147 cites W2180555938 @default.
• W3205584147 cites W2258036625 @default.
• W3205584147 cites W2316322202 @default.
• W3205584147 cites W2324483428 @default.
• W3205584147 cites W2328382804 @default.
• W3205584147 cites W2346511364 @default.
• W3205584147 cites W2415024230 @default.
• W3205584147 cites W2515184341 @default.
• W3205584147 cites W2563317460 @default.
• W3205584147 cites W2576500360 @default.
• W3205584147 cites W2580913788 @default.
• W3205584147 cites W2600375641 @default.
• W3205584147 cites W2620552827 @default.
• W3205584147 cites W2733049073 @default.
• W3205584147 cites W2766535472 @default.
• W3205584147 cites W2773491296 @default.
• W3205584147 cites W2883374185 @default.
• W3205584147 cites W2908543224 @default.
• W3205584147 cites W2950676896 @default.
• W3205584147 cites W2967848458 @default.
• W3205584147 cites W2994814697 @default.
• W3205584147 cites W3004207587 @default.
• W3205584147 cites W3008317185 @default.
• W3205584147 cites W3009022702 @default.
• W3205584147 cites W3087382172 @default.
• W3205584147 cites W3098069061 @default.
• W3205584147 cites W3101352084 @default.
• W3205584147 cites W3130131296 @default.
• W3205584147 cites W3161036294 @default.
• W3205584147 cites W3199299129 @default.
• W3205584147 doi "https://doi.org/10.1021/acsnano.1c06226" @default.
• W3205584147 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34633170" @default.
• W3205584147 hasPublicationYear "2021" @default.
• W3205584147 type Work @default.
• W3205584147 sameAs 3205584147 @default.
• W3205584147 citedByCount "8" @default.
• W3205584147 countsByYear W32055841472022 @default.
• W3205584147 countsByYear W32055841472023 @default.
• W3205584147 crossrefType "journal-article" @default.
• W3205584147 hasAuthorship W3205584147A5002229288 @default.
• W3205584147 hasAuthorship W3205584147A5005749804 @default.
• W3205584147 hasAuthorship W3205584147A5008948855 @default.
• W3205584147 hasAuthorship W3205584147A5013678020 @default.
• W3205584147 hasAuthorship W3205584147A5021066913 @default.
• W3205584147 hasAuthorship W3205584147A5073782691 @default.
• W3205584147 hasAuthorship W3205584147A5079168781 @default.
• W3205584147 hasAuthorship W3205584147A5086689121 @default.
• W3205584147 hasAuthorship W3205584147A5091403848 @default.
• W3205584147 hasBestOaLocation W32055841472 @default.
• W3205584147 hasConcept C119889771 @default.
• W3205584147 hasConcept C127413603 @default.
• W3205584147 hasConcept C138631740 @default.
• W3205584147 hasConcept C140807948 @default.
• W3205584147 hasConcept C151730666 @default.
• W3205584147 hasConcept C159467904 @default.
• W3205584147 hasConcept C161790260 @default.
• W3205584147 hasConcept C171250308 @default.
• W3205584147 hasConcept C175708663 @default.
• W3205584147 hasConcept C178790620 @default.

• next