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- W3205671365 abstract "Abstract Non‐covalent interactions involving multicenter multielectron skeletons such as boron clusters are rare. Now, a non‐covalent interaction, the nido‐cage⋅⋅⋅π bond, is discovered based on the boron cluster C 2 B 9 H 12 − and an aromatic π system. The X‐ray diffraction studies indicate that the nido‐cage⋅⋅⋅π bonding presents parallel‐displaced or T‐shaped geometries. The contacting distance between cage and π ring varies with the type and the substituent of the aromatic ring. Theoretical calculations reveal that this nido‐cage⋅⋅⋅π bond shares a similar nature to the conventional anion⋅⋅⋅π or π⋅⋅⋅π bonds found in classical aromatic ring systems. This nido‐cage⋅⋅⋅π interaction induces variable photophysical properties such as aggregation‐induced emission and aggregation‐caused quenching in one molecule. This work offers an overall understanding towards the boron cluster‐based non‐covalent bond and opens a door to investigate its properties." @default.
- W3205671365 created "2021-10-25" @default.
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- W3205671365 date "2020-04-06" @default.
- W3205671365 modified "2023-10-06" @default.
- W3205671365 title "The <i>nido</i> ‐Cage⋅⋅⋅π Bond: A Non‐covalent Interaction between Boron Clusters and Aromatic Rings and Its Applications" @default.
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- W3205671365 doi "https://doi.org/10.1002/anie.201915290" @default.
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