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- W3205842313 abstract "A series of isotactic, semicrystalline vinyl ether copolymers (up to 94% <i>meso</i> diads) were synthesized using a chiral BINOL-based phosphoric acid in combination with a titanium Lewis acid. This stereoselective cationic polymerization enabled the systematic tuning of both glass-transition (<i>T</i><sub>g</sub>) and melting temperature (<i>T</i><sub>m</sub>) in copolymers derived from alkyl vinyl ethers (<i>i.e.</i>, ethyl, butyl, isobutyl). Additionally, a vinyl ether comonomer bearing an acyl-protected alcohol was utilized as a platform for post-functionalization. Copolymers containing the masked alcohols were shown to undergo facile deprotection and subsequent coupling with a desired acid chloride. Collectively, these results highlight the diverse material properties and expanded chemical space accessible through stereoselective cationic polymerization mediated by a chiral anion." @default.
- W3205842313 created "2021-10-25" @default.
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- W3205842313 date "2019-09-27" @default.
- W3205842313 modified "2023-09-27" @default.
- W3205842313 title "Polar Thermoplastics with Tunable Physical Properties Enabled by the Stereoregular Copolymerization of Vinyl Ethers" @default.
- W3205842313 cites W2094745278 @default.
- W3205842313 cites W2270113823 @default.
- W3205842313 doi "https://doi.org/10.26434/chemrxiv.9904985.v1" @default.
- W3205842313 hasPublicationYear "2019" @default.
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