FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3205929761> ?p ?o ?g. }

• W3205929761 endingPage "12335" @default.
• W3205929761 startingPage "12326" @default.
• W3205929761 abstract "Catalytic reduction of CO2 to valuable products is an attractive route for CO2 recycling. CeO2-supported Cu catalysts have shown high activity and selectivity for the hydrogenation of CO2 to CO. To uncover the origin of their high performance, we prepared a practical and well-defined model of Cu/CeO2–x catalysts with Cu nanoparticles dispersed on a CeO2–x support. We studied the structure and catalytic activity of the practical catalyst and the evolution of the active phase and surface intermediates using near-ambient-pressure X-ray photoelectron spectroscopy (NAP-XPS) over the model catalyst under CO2 hydrogenation conditions. For both model and practical catalysts, metallic copper and partially reduced ceria with oxygen vacancies were found to be active sites for the reduction of CO2 to CO. Over the model catalyst, partial covering of Cu by CeO2–x and diffusion of Cu into CeO2–x was observed, suggesting that a strong interaction between Cu and CeO2–x was favored during CO2 hydrogenation. The surface analysis results indicated that the CO2 hydrogenation proceeded through the following steps: activation of CO2 in the form of carbonate on the surface of CeO2–x, hydrogenation of carbonate to formate on the surface of Cu by the dissociated H2, and conversion of formate to CO. This work provides direct experimental evidence on the surface properties of Cu and ceria during the RWGS reaction and the activation and hydrogenation processes of CO2 over the Cu/CeO2–x surface for a high RWGS catalytic performance." @default.
• W3205929761 created "2021-10-25" @default.
• W3205929761 creator A5005895018 @default.
• W3205929761 creator A5045667730 @default.
• W3205929761 creator A5058486187 @default.
• W3205929761 creator A5071738074 @default.
• W3205929761 creator A5088549016 @default.
• W3205929761 creator A5088577552 @default.
• W3205929761 date "2021-10-12" @default.
• W3205929761 modified "2023-10-14" @default.
• W3205929761 title "Revealing the Surface Chemistry for CO₂ Hydrogenation on Cu/CeO_2–<i>x</i> Using Near-Ambient-Pressure X-ray Photoelectron Spectroscopy" @default.
• W3205929761 cites W164929036 @default.
• W3205929761 cites W1783493372 @default.
• W3205929761 cites W1967415751 @default.
• W3205929761 cites W1971876886 @default.
• W3205929761 cites W1972896636 @default.
• W3205929761 cites W1984716937 @default.
• W3205929761 cites W1991692033 @default.
• W3205929761 cites W1995761354 @default.
• W3205929761 cites W2011377242 @default.
• W3205929761 cites W2017943582 @default.
• W3205929761 cites W2018541815 @default.
• W3205929761 cites W2018926617 @default.
• W3205929761 cites W2026202217 @default.
• W3205929761 cites W2033829943 @default.
• W3205929761 cites W2044358811 @default.
• W3205929761 cites W2051796629 @default.
• W3205929761 cites W2059715814 @default.
• W3205929761 cites W2064104391 @default.
• W3205929761 cites W2091779828 @default.
• W3205929761 cites W2102360200 @default.
• W3205929761 cites W2105680920 @default.
• W3205929761 cites W2109613653 @default.
• W3205929761 cites W2127492808 @default.
• W3205929761 cites W2148587445 @default.
• W3205929761 cites W2193795799 @default.
• W3205929761 cites W2265853247 @default.
• W3205929761 cites W2300652854 @default.
• W3205929761 cites W2331030043 @default.
• W3205929761 cites W2345834140 @default.
• W3205929761 cites W2418452057 @default.
• W3205929761 cites W2521314152 @default.
• W3205929761 cites W2587925500 @default.
• W3205929761 cites W2600566292 @default.
• W3205929761 cites W2625918461 @default.
• W3205929761 cites W2735610389 @default.
• W3205929761 cites W2747629573 @default.
• W3205929761 cites W2752381118 @default.
• W3205929761 cites W2804553700 @default.
• W3205929761 cites W2857136719 @default.
• W3205929761 cites W2878663886 @default.
• W3205929761 cites W2886869886 @default.
• W3205929761 cites W2889266342 @default.
• W3205929761 cites W2889837234 @default.
• W3205929761 cites W2892181609 @default.
• W3205929761 cites W2900869555 @default.
• W3205929761 cites W2906882340 @default.
• W3205929761 cites W2935835050 @default.
• W3205929761 cites W2948199543 @default.
• W3205929761 cites W2948583960 @default.
• W3205929761 cites W2963739785 @default.
• W3205929761 cites W2972191735 @default.
• W3205929761 cites W2995455660 @default.
• W3205929761 cites W3002843872 @default.
• W3205929761 cites W3014333059 @default.
• W3205929761 cites W3022393009 @default.
• W3205929761 cites W3045691659 @default.
• W3205929761 cites W3071973204 @default.
• W3205929761 cites W3085168670 @default.
• W3205929761 cites W3085524505 @default.
• W3205929761 cites W3098140352 @default.
• W3205929761 cites W3111919667 @default.
• W3205929761 cites W3126665740 @default.
• W3205929761 cites W3135422091 @default.
• W3205929761 cites W3173614690 @default.
• W3205929761 cites W4376999353 @default.
• W3205929761 cites W2189255995 @default.
• W3205929761 doi "https://doi.org/10.1021/acsaem.1c02146" @default.
• W3205929761 hasPublicationYear "2021" @default.
• W3205929761 type Work @default.
• W3205929761 sameAs 3205929761 @default.
• W3205929761 citedByCount "7" @default.
• W3205929761 countsByYear W32059297612022 @default.
• W3205929761 countsByYear W32059297612023 @default.
• W3205929761 crossrefType "journal-article" @default.
• W3205929761 hasAuthorship W3205929761A5005895018 @default.
• W3205929761 hasAuthorship W3205929761A5045667730 @default.
• W3205929761 hasAuthorship W3205929761A5058486187 @default.
• W3205929761 hasAuthorship W3205929761A5071738074 @default.
• W3205929761 hasAuthorship W3205929761A5088549016 @default.
• W3205929761 hasAuthorship W3205929761A5088577552 @default.
• W3205929761 hasConcept C118792377 @default.
• W3205929761 hasConcept C121332964 @default.
• W3205929761 hasConcept C127413603 @default.
• W3205929761 hasConcept C143895478 @default.
• W3205929761 hasConcept C147789679 @default.
• W3205929761 hasConcept C155672457 @default.
• W3205929761 hasConcept C161790260 @default.

• next