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- W3205943333 abstract "The organocatalytic asymmetric synthesis of enantiopure bis-heterocyclic molecules containing pyrazole and isoxazole under mild reaction conditions has been reported via a low-catalyst loading Michael addition reaction of pyrazolyl nitroalkenes with 1,3-dicarbonyl derivatives. 4-Substituted pyrazole derivatives were obtained in 60-87% yields and with 82-97% ee. These pyrazolyl derivatives are further transformed into chiral bis-heterocyclic derivatives in up to 82% yields and up to 99% ee. The synthesized pyrazole and isoxazole based bis-heterocyclic derivatives are potential bio-active molecules expected to have significant applications. Additionally, the synthesis of these bis-heterocycles can efficiently be carried out in one pot without any loss of enantiopurity, which further adds to its significance." @default.
- W3205943333 created "2021-10-25" @default.
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- W3205943333 date "2021-01-01" @default.
- W3205943333 modified "2023-10-17" @default.
- W3205943333 title "Low catalyst loading enabled organocatalytic synthesis of chiral bis-heterocyclic frameworks containing pyrazole and isoxazole" @default.
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- W3205943333 doi "https://doi.org/10.1039/d1ob01313k" @default.
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