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- W3206168320 abstract "The compatibility of photochemistry with solid-phase peptide synthesis is demonstrated via photochemical hydroalkylation to form C(sp3)-C(sp3) bonds between on-resin Giese acceptors and redox-active esters. Both iridium-based photocatalysts and Hantszch ester led to high yields, with final reaction conditions producing full conversions within 30 min under ambient conditions. The chemistry is compatible with a broad range of peptide side chains, redox-active esters, and resin. These conditions represent the first example of photochemical peptide modifications on resin." @default.
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- W3206168320 date "2021-10-14" @default.
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- W3206168320 title "Solid-Phase Photochemical Decarboxylative Hydroalkylation of Peptides" @default.
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- W3206168320 doi "https://doi.org/10.1021/acs.orglett.1c02928" @default.
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