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- W3206456987 abstract "Alkylidene ketenes typically display high intrinsic reactivity, impeding isolation on a preparative scale. Herein, we report the synthesis of alkylidene ketenes by reaction of imidazole-based diazoolefins with carbon monoxide. The good thermal stability of these heterocumulenes allows for characterization by single crystal X-ray diffraction. N-Heterocyclic alkylidene ketenes can be used as C-donor ligands for transition and main group metals, as evidenced by the isolation of complexes with AuCl, RhCl(CO)2, PdCl(C3H5) and GaCl3." @default.
- W3206456987 created "2021-10-25" @default.
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- W3206456987 date "2021-01-01" @default.
- W3206456987 modified "2023-10-16" @default.
- W3206456987 title "Synthesis, structural characterization, and coordination chemistry of imidazole-based alkylidene ketenes" @default.
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- W3206456987 doi "https://doi.org/10.1039/d1cc05161j" @default.
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