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- W3206526588 abstract "Abstract A methodology is reported for visible‐light‐promoted synthesis of unsymmetrical chalcogenides enabled by dimsyl anion in the absence of transition‐metals or photoredox catalysts. The cross‐coupling reaction between aryl halides and diaryl dichalcogenides proceeds with electron‐rich, electron‐poor, and heteroaromatic moieties. Mechanistic investigations using UV‐Vis spectroscopy, time‐dependent density functional theory (TD‐DFT) calculations, and control reactions suggest that dimsyl anion forms an electron‐donor‐acceptor (EDA) complex capable of absorbing blue light, leading to a charge transfer responsible for generation of aryl radicals from aryl halides. This previously unreported mechanistic pathway may be applied to other light‐induced transformations performed in DMSO in the presence of bases and aryl halides. magnified image" @default.
- W3206526588 created "2021-10-25" @default.
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- W3206526588 date "2021-10-26" @default.
- W3206526588 modified "2023-10-10" @default.
- W3206526588 title "Dimsyl Anion Enables Visible‐Light‐Promoted Charge Transfer in Cross‐Coupling Reactions of Aryl Halides" @default.
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- W3206526588 doi "https://doi.org/10.1002/adsc.202101052" @default.
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