Matches in SemOpenAlex for { <https://semopenalex.org/work/W3206548441> ?p ?o ?g. }
- W3206548441 endingPage "2593" @default.
- W3206548441 startingPage "2585" @default.
- W3206548441 abstract "Abstract Benzene bisamides are promising building blocks for supramolecular nano‐objects. Their functionality depends on morphology and surface properties. However, a direct link between surface properties and molecular structure itself is missing for this material class. Here, we investigate this interplay for two series of 1,4‐benzene bisamides with symmetric and asymmetric peripheral substitution. We elucidated the crystal structures, determined the nano‐object morphologies and derived the wetting behaviour of the preferentially exposed surfaces. The crystal structures were solved by combining single‐crystal and powder X‐ray diffraction, solid‐state NMR spectroscopy and computational modelling. Bulky side groups, here t‐butyl groups, serve as a structure‐directing motif into a packing pattern, which favours the formation of thin platelets. The use of slim peripheral groups on both sides, in our case linear perfluorinated, alkyl chains, self‐assemble the benzene bisamides into a second packing pattern which leads to ribbon‐like nano‐objects. For both packing types, the preferentially exposed surfaces consist of the ends of the peripheral groups. Asymmetric substitution with bulky and slim groups leads to an ordered alternating arrangement of the groups exposed to the surface. This allows the hydrophobicity of the surfaces to be gradually altered. We thus identified two leitmotifs for molecular packings of benzene bisamides providing the missing link between the molecular structure, the anisotropic morphologies and adjustable surface properties of the supramolecular nano‐objects." @default.
- W3206548441 created "2021-10-25" @default.
- W3206548441 creator A5003995058 @default.
- W3206548441 creator A5032535843 @default.
- W3206548441 creator A5040285686 @default.
- W3206548441 creator A5056485744 @default.
- W3206548441 creator A5084905244 @default.
- W3206548441 date "2021-11-08" @default.
- W3206548441 modified "2023-09-24" @default.
- W3206548441 title "Crystal engineering of supramolecular 1,4‐benzene bisamides by side chain modification ‐ towards tuneable anisotropic morphologies and surfaces" @default.
- W3206548441 cites W1594580501 @default.
- W3206548441 cites W1967562911 @default.
- W3206548441 cites W1969360633 @default.
- W3206548441 cites W1970656836 @default.
- W3206548441 cites W1976004525 @default.
- W3206548441 cites W1985785563 @default.
- W3206548441 cites W1990740507 @default.
- W3206548441 cites W1990766817 @default.
- W3206548441 cites W1994684330 @default.
- W3206548441 cites W1994846237 @default.
- W3206548441 cites W1998920258 @default.
- W3206548441 cites W2006122386 @default.
- W3206548441 cites W2007068681 @default.
- W3206548441 cites W2009323525 @default.
- W3206548441 cites W2016260972 @default.
- W3206548441 cites W2016325227 @default.
- W3206548441 cites W2016943360 @default.
- W3206548441 cites W2018536346 @default.
- W3206548441 cites W2019167263 @default.
- W3206548441 cites W2023074259 @default.
- W3206548441 cites W2030976617 @default.
- W3206548441 cites W2032221671 @default.
- W3206548441 cites W2036113194 @default.
- W3206548441 cites W2038028204 @default.
- W3206548441 cites W2043026140 @default.
- W3206548441 cites W2046345163 @default.
- W3206548441 cites W2050312594 @default.
- W3206548441 cites W2050351250 @default.
- W3206548441 cites W2055516309 @default.
- W3206548441 cites W2056280638 @default.
- W3206548441 cites W2058739416 @default.
- W3206548441 cites W2059477440 @default.
- W3206548441 cites W2059885388 @default.
- W3206548441 cites W2063708840 @default.
- W3206548441 cites W2065078046 @default.
- W3206548441 cites W2067802660 @default.
- W3206548441 cites W2070627981 @default.
- W3206548441 cites W2085822586 @default.
- W3206548441 cites W2089067595 @default.
- W3206548441 cites W2092653651 @default.
- W3206548441 cites W2103837951 @default.
- W3206548441 cites W2107746113 @default.
- W3206548441 cites W2110537606 @default.
- W3206548441 cites W2121580007 @default.
- W3206548441 cites W2129417901 @default.
- W3206548441 cites W2134440309 @default.
- W3206548441 cites W2135020188 @default.
- W3206548441 cites W2139844301 @default.
- W3206548441 cites W2150249789 @default.
- W3206548441 cites W2150286722 @default.
- W3206548441 cites W2158659641 @default.
- W3206548441 cites W2159752439 @default.
- W3206548441 cites W2163956997 @default.
- W3206548441 cites W2170309222 @default.
- W3206548441 cites W2188040727 @default.
- W3206548441 cites W2230728100 @default.
- W3206548441 cites W2330716204 @default.
- W3206548441 cites W2339207419 @default.
- W3206548441 cites W2566520555 @default.
- W3206548441 cites W2568911963 @default.
- W3206548441 cites W2585206920 @default.
- W3206548441 cites W2586430830 @default.
- W3206548441 cites W2586603588 @default.
- W3206548441 cites W2591867430 @default.
- W3206548441 cites W2600884580 @default.
- W3206548441 cites W2602955084 @default.
- W3206548441 cites W2603679955 @default.
- W3206548441 cites W2742255552 @default.
- W3206548441 cites W2784103179 @default.
- W3206548441 cites W2883505356 @default.
- W3206548441 cites W2903130016 @default.
- W3206548441 cites W2912898643 @default.
- W3206548441 cites W2913903767 @default.
- W3206548441 cites W2916467126 @default.
- W3206548441 cites W2936233161 @default.
- W3206548441 cites W2963928430 @default.
- W3206548441 cites W2975791946 @default.
- W3206548441 cites W3004709547 @default.
- W3206548441 cites W3008452922 @default.
- W3206548441 cites W3011984279 @default.
- W3206548441 cites W3025702636 @default.
- W3206548441 cites W3118767215 @default.
- W3206548441 cites W3124597223 @default.
- W3206548441 cites W3125289091 @default.
- W3206548441 cites W3149127060 @default.
- W3206548441 cites W3206548441 @default.
- W3206548441 cites W375700860 @default.
- W3206548441 cites W68096893 @default.