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- W3206558193 abstract "GdFeTeO6 and GdGaTeO6 have been prepared and their structures refined by the Rietveld method. Both are superstructures of the rosiaite type (space group P3¯1c). Their thermodynamic properties have been investigated by means of magnetization M and specific heat Cp measurements, evidencing the formation of the long-range antiferromagnetic order at TN = 2.4 K in the former compound and paramagnetic behavior down to 2 K in the latter compound. Large magnetocaloric effect allows considering GdFeTeO6 for the magnetic refrigeration at liquid hydrogen stage. Density functional theory calculations produce estimations of leading Gd-Gd, Gd-Fe and Fe-Fe interactions suggesting unique chiral 120° magnetic structure of Fe3+ (S = 5/2) moments and Gd3+ (J = 7/2) moments rotating in opposite directions (clockwise/anticlockwise) within weakly coupled layers of the rosiaite type crystal structure." @default.
- W3206558193 created "2021-10-25" @default.
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- W3206558193 date "2021-10-10" @default.
- W3206558193 modified "2023-09-26" @default.
- W3206558193 title "Chirality and Magnetocaloricity in GdFeTeO6 as Compared to GdGaTeO6" @default.
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- W3206558193 doi "https://doi.org/10.3390/ma14205954" @default.
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