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- W3206573920 endingPage "18260" @default.
- W3206573920 startingPage "18251" @default.
- W3206573920 abstract "Red-light responsiveness of photoswitches is a highly desired property for many important application areas such as biology or material sciences. The main approach to elicit this property uses strategic substitution of long-known photoswitch motives such as azobenzenes or diarylethenes. Only very few photoswitches possess inherent red-light absorption of their core chromophore structures. Here, we present a strategy to convert the long-known purple indirubin dye into a prolific red-light-responsive photoswitch. In a supramolecular approach, its photochromism can be changed from a negative to a positive one, while at the same time, significantly higher yields of the metastable E-isomer are obtained upon irradiation. E- to Z-photoisomerization can then also be induced by red light of longer wavelengths. Indirubin therefore represents a unique example of reversible photoswitching using entirely red light for both switching directions." @default.
- W3206573920 created "2021-10-25" @default.
- W3206573920 creator A5010784491 @default.
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- W3206573920 creator A5042562320 @default.
- W3206573920 creator A5059139349 @default.
- W3206573920 creator A5081070456 @default.
- W3206573920 date "2021-10-19" @default.
- W3206573920 modified "2023-10-17" @default.
- W3206573920 title "All-Red-Light Photoswitching of Indirubin Controlled by Supramolecular Interactions" @default.
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- W3206573920 doi "https://doi.org/10.1021/jacs.1c08206" @default.
- W3206573920 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34665961" @default.