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- W3206591939 abstract "Abstract The readily scalable asymmetric synthesis of the chiral chromone derivatives functionalized at position 2 via electrophilic enantioselective olefination of the chromone core with nitroolefins and ß , γ ‐unsaturated α ‐ketoesters in the presence of simple C 2 ‐symmetric tertiary amine‐squaramide catalyst was developed. The reaction products were obtained in 80–99% yield with 89–99% ee in 95% EtOH. The absolute configurations of the synthesized chromone derivatives were unambiguously established by transformation of compound ( R )‐ 3 aa to known methyl ( R )‐ β ‐nitro‐ α ‐phenylpropionate and by the single crystal XRD analysis of compounds ( R , S )‐ 5 aa and ( R , S )‐ 5 ab . Catalyst V poorly soluble in common organic solvents could be easily separated from the reaction mixture and reused up to 10 catalytic cycles. Catalytic hydrogenation and esterification reactions of the synthesized compounds were carried out to demonstrate synthetic potential of the developed procedure. magnified image" @default.
- W3206591939 created "2021-10-25" @default.
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- W3206591939 date "2021-10-28" @default.
- W3206591939 modified "2023-09-24" @default.
- W3206591939 title "Asymmetric Conjugate Addition of 3‐Hydroxychromen‐4‐Ones to Electron‐Deficient Olefins Catalyzed by Recyclable C<sub>2</sub>‐Symmetric Squaramide" @default.
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- W3206591939 doi "https://doi.org/10.1002/adsc.202101019" @default.
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