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- W3206740298 endingPage "15711" @default.
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- W3206740298 abstract "A highly regio- and diastereoselective approach for the synthesis of phosphate substituted dihydrocoumarins via Brønsted base catalyzed [1,2]-phospha-Brook rearrangement is reported. The two-step, one-pot Michael addition of α-phosphonyloxy enolates proceeds by coupling of dialkyl phosphite and α-ketoesters to o-quinone methides, followed by an intramolecular cyclization, providing 3,4-dihydrocoumarin frameworks." @default.
- W3206740298 created "2021-10-25" @default.
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- W3206740298 date "2021-10-12" @default.
- W3206740298 modified "2023-10-18" @default.
- W3206740298 title "Stereoselective Synthesis of Dihydrocoumarins via [1,2]-Phospha-Brook Rearrangement in Three-Component Coupling Reaction of α-Ketoesters, <i>o</i>-Quinone Methides, and Dialkyl Phosphites" @default.
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- W3206740298 doi "https://doi.org/10.1021/acs.joc.1c01414" @default.
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