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• W3206818667 startingPage "153486" @default.
• W3206818667 abstract "The asymmetric synthesis of (-)-dihydrospirotryprostatin B ( 3 ), a cytostatic spiro[pyrrolidine-3,3′-oxindole] alkaloid, has been accomplished in 8 longest linear steps (LLS) from commercially available amino acids. The key step of the synthetic approach consists of the tandem Michael addition of oxindole derived from dipeptide diketopiperazine to alkynone, leading to the rapid construction of the spiro[pyrrolidine-3,3′-oxindole] scaffold with the consecutive quaternary spiro carbon center and chiral tertiary amine being diastereoselectively established." @default.
• W3206818667 created "2021-10-25" @default.
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• W3206818667 date "2021-11-01" @default.
• W3206818667 modified "2023-10-13" @default.
• W3206818667 title "A concise synthesis of (-)-dihydrospirotryprostatin B via tandem Michael addition" @default.
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• W3206818667 doi "https://doi.org/10.1016/j.tetlet.2021.153486" @default.
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