Matches in SemOpenAlex for { <https://semopenalex.org/work/W3206858045> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W3206858045 abstract "Dipeptides are known to spontaneously cyclize to diketopiperazines, and in some cases these cyclic dipeptides have been shown to self-assemble to form supramolecular nanostructures.<b> </b>Herein, we demonstrate the <i>in situ</i> cyclization of dipeptide methyl esters in aqueous buffer by intramolecular aminolysis, leading to the formation of diverse supramolecular nanostructures. The chemical nature of the amino acid side chains dictates the supramolecular arrangement and resulting nanoscale architectures. For c[LF], supramolecular gels are formed, and the concentration of starting materials influences the mechanical properties of hydrogels. Moreover, by adding metalloporphyrin to the starting dipeptide ester solution, these become incorporated through cooperative assembly,<b> </b>resulting in the formation of nanofibers able to catalyse the oxidation of organic phenol in water. The approach taken here, which combines the chemically activated assembly with the versatility of short peptides might pave the way for achieving the spontaneous formation of supramolecular order and function using simple building blocks.<br>" @default.
- W3206858045 created "2021-10-25" @default.
- W3206858045 creator A5012580097 @default.
- W3206858045 creator A5015057973 @default.
- W3206858045 creator A5019096622 @default.
- W3206858045 creator A5043861131 @default.
- W3206858045 creator A5055983732 @default.
- W3206858045 creator A5061767374 @default.
- W3206858045 creator A5063033654 @default.
- W3206858045 creator A5075185586 @default.
- W3206858045 creator A5079790850 @default.
- W3206858045 date "2020-01-24" @default.
- W3206858045 modified "2023-09-26" @default.
- W3206858045 title "Spontaneous Aminolytic Cyclization and Self-Assembly of Dipeptide Methyl Esters in Water" @default.
- W3206858045 doi "https://doi.org/10.26434/chemrxiv.11637312.v1" @default.
- W3206858045 hasPublicationYear "2020" @default.
- W3206858045 type Work @default.
- W3206858045 sameAs 3206858045 @default.
- W3206858045 citedByCount "0" @default.
- W3206858045 crossrefType "posted-content" @default.
- W3206858045 hasAuthorship W3206858045A5012580097 @default.
- W3206858045 hasAuthorship W3206858045A5015057973 @default.
- W3206858045 hasAuthorship W3206858045A5019096622 @default.
- W3206858045 hasAuthorship W3206858045A5043861131 @default.
- W3206858045 hasAuthorship W3206858045A5055983732 @default.
- W3206858045 hasAuthorship W3206858045A5061767374 @default.
- W3206858045 hasAuthorship W3206858045A5063033654 @default.
- W3206858045 hasAuthorship W3206858045A5075185586 @default.
- W3206858045 hasAuthorship W3206858045A5079790850 @default.
- W3206858045 hasBestOaLocation W32068580451 @default.
- W3206858045 hasConcept C108586683 @default.
- W3206858045 hasConcept C161790260 @default.
- W3206858045 hasConcept C171250308 @default.
- W3206858045 hasConcept C178790620 @default.
- W3206858045 hasConcept C184651966 @default.
- W3206858045 hasConcept C185592680 @default.
- W3206858045 hasConcept C192562407 @default.
- W3206858045 hasConcept C21951064 @default.
- W3206858045 hasConcept C26856880 @default.
- W3206858045 hasConcept C2777998946 @default.
- W3206858045 hasConcept C2779138802 @default.
- W3206858045 hasConcept C2779281246 @default.
- W3206858045 hasConcept C32909587 @default.
- W3206858045 hasConcept C55493867 @default.
- W3206858045 hasConcept C71240020 @default.
- W3206858045 hasConcept C75079739 @default.
- W3206858045 hasConcept C91129048 @default.
- W3206858045 hasConcept C93275456 @default.
- W3206858045 hasConceptScore W3206858045C108586683 @default.
- W3206858045 hasConceptScore W3206858045C161790260 @default.
- W3206858045 hasConceptScore W3206858045C171250308 @default.
- W3206858045 hasConceptScore W3206858045C178790620 @default.
- W3206858045 hasConceptScore W3206858045C184651966 @default.
- W3206858045 hasConceptScore W3206858045C185592680 @default.
- W3206858045 hasConceptScore W3206858045C192562407 @default.
- W3206858045 hasConceptScore W3206858045C21951064 @default.
- W3206858045 hasConceptScore W3206858045C26856880 @default.
- W3206858045 hasConceptScore W3206858045C2777998946 @default.
- W3206858045 hasConceptScore W3206858045C2779138802 @default.
- W3206858045 hasConceptScore W3206858045C2779281246 @default.
- W3206858045 hasConceptScore W3206858045C32909587 @default.
- W3206858045 hasConceptScore W3206858045C55493867 @default.
- W3206858045 hasConceptScore W3206858045C71240020 @default.
- W3206858045 hasConceptScore W3206858045C75079739 @default.
- W3206858045 hasConceptScore W3206858045C91129048 @default.
- W3206858045 hasConceptScore W3206858045C93275456 @default.
- W3206858045 hasLocation W32068580451 @default.
- W3206858045 hasLocation W32068580452 @default.
- W3206858045 hasLocation W32068580453 @default.
- W3206858045 hasOpenAccess W3206858045 @default.
- W3206858045 hasPrimaryLocation W32068580451 @default.
- W3206858045 hasRelatedWork W11345025 @default.
- W3206858045 hasRelatedWork W12557990 @default.
- W3206858045 hasRelatedWork W15114827 @default.
- W3206858045 hasRelatedWork W17823504 @default.
- W3206858045 hasRelatedWork W18030136 @default.
- W3206858045 hasRelatedWork W23307996 @default.
- W3206858045 hasRelatedWork W29804617 @default.
- W3206858045 hasRelatedWork W30038590 @default.
- W3206858045 hasRelatedWork W3403773 @default.
- W3206858045 hasRelatedWork W4733733 @default.
- W3206858045 isParatext "false" @default.
- W3206858045 isRetracted "false" @default.
- W3206858045 magId "3206858045" @default.
- W3206858045 workType "article" @default.