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• W3206953692 abstract "We present here a metal-free, visible-light- and triphenylphosphine-mediated intermolecular, reductive amination between nitroarenes and boronic acids at ambient temperature without any photocatalyst. Mechanistically, a slow reduction of nitroarenes to a nitroso and, finally, a nitrene intermediate occurs that leads to the amination product with concomitant 1,2-aryl/-alkyl migration from a boronate complex. A wide range of nitroarenes underwent C-N coupling with aryl-/alkylboronic acids providing high yields." @default.
• W3206953692 created "2021-10-25" @default.
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• W3206953692 date "2021-10-13" @default.
• W3206953692 modified "2023-10-15" @default.
• W3206953692 title "Visible-Light- and PPh₃-Mediated Direct C–N Coupling of Nitroarenes and Boronic Acids at Ambient Temperature" @default.
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• W3206953692 doi "https://doi.org/10.1021/acs.orglett.1c03343" @default.
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• W3206953692 hasPublicationYear "2021" @default.
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