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- W3207165961 abstract "Abstract The pressure‐driven force‐electric conversion materials with extremely rapid response time have been widely used in mining, defense, and energy areas. The discharge process by the force‐electric conversion effect in ferroelectrics is dominated by polar‐nonpolar phase transformation. In this work, (Pb 0.985 La 0.01 )(Zr x Ti 1‐ x )O 3 (PLZT, x = 0.85–0.94) ceramics is designed by tunning Zr 4+ /Ti 4+ ratio and aliovalent La doping to achieve high remnant polarization ( P r ) and excellent temperature stability. We focus on the pressure‐driven depolarization in PLZT ceramics, and their corresponding phase structure, ferroelectric properties, dielectric properties, and thermal depolarization. In PLZT ( x = 0.93) ceramics, the original polarization P 0 increases to 43.42 μC/cm 2 . The pressure‐driven depolarization releases 37.66 μC/cm 2 with the depolarization proportion of 86.73%, which is attributed to irreversible ferroelectric‐antiferroelectric phase transition. It also exhibits excellent temperature stability up to 120°C (> 36 μC/cm 2 ). This work provides a high‐performance alternative to Pb(Zr 0.95 Ti 0.05 )O 3 and guidance for the development of pulse power energy conversion devices." @default.
- W3207165961 created "2021-10-25" @default.
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- W3207165961 date "2021-10-23" @default.
- W3207165961 modified "2023-10-16" @default.
- W3207165961 title "Enhanced pressure‐driven force‐electric conversion effect for (Pb,La)(Zr,Ti)O <sub>3</sub> ferroelectric ceramics" @default.
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- W3207165961 doi "https://doi.org/10.1111/jace.18164" @default.
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