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- W3207595395 abstract "A series of 1D-, 2D-, and 3D-hydrogen-bonded organic frameworks (1D-, 2D-, and 3D-HOFs) force-driven by macrocyclic multifluorine tectons (F-tectons) was constructed on the basis of burgeoning multifluorinated diaminoterephthalates (25, 345, and 26). Crystalline 25 gave ladder-shaped 1D-HOFs containing one kind of macrocyclic F-tecton looped by two F···H(CH3) hydrogen bonds in competition with strong π···π and π···H(CH3) interactions. Crystalline 345 gave layer-by-layer translational 2D-HOFs containing hierarchically macrocyclic F-tectons looped by 8-fold hydrogen bonds, including three F···H(CH3), three ═O···HN and two ArC···H(CH3) prior to weak π···π interactions. Crystalline 26 possessed 2-fold interpenetrated 3D-HOFs containing hierarchically macrocyclic F-tectons looped by F···H(CH3), ArH···F, and ArH···F···H(CH3) hydrogen bonds and interpenatrated by strong π···π interactions. In addition to that, the electron-withdrawing multifluorination of diaminoterephthalates caused an optical blue shift with wide optical energy gaps (2.43–2.51 eV) for 25, 345, and 26 in solution and a wide optical band gap (2.31 eV) for 345 in the film state. The multifluorination effect confirms an interesting trend that more F atoms bring in deeper highest occupied molecular orbital (HOMO)/lowest unoccupied molecular orbital (LUMO) energy levels (345 vs 25/26) and also regioisomerism confirms that farther F atoms bring in deeper HOMO/LUMO energy levels (25 vs 26)." @default.
- W3207595395 created "2021-10-25" @default.
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- W3207595395 date "2021-10-14" @default.
- W3207595395 modified "2023-09-26" @default.
- W3207595395 title "Wide-Gap 1D-, 2D-, and 3D-Hydrogen-Bonded Organic Frameworks Hierarchically Weaved by Macrocyclic Supramolecular Multifluorine Tectons" @default.
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- W3207595395 doi "https://doi.org/10.1021/acs.cgd.1c00622" @default.
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