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- W3207595439 abstract "The dibasic and monobasic calcium salts of o-tolidine-6,6′-disulfonic acid, tetraaqua(4,4′-diamino-5,5′-dimethyl-1,1′-biphenyl-2,2′-disulfonato-O:O') calcium, [Ca(C14H14N2O6S2)(H2O)4]n, (I), and hexaaqua(4-amino-4′-ammonio-5,5′-dimethyl-1,1′-biphenyl-2,2′-disulfonato-O) calcium 4-amino-4′-ammonio-5,5′-dimethyl-1,1′-biphenyl-2,2′-disulfonate hexahydrate, [Ca(C14H15N2O6S2)(H2O)6](C14H15N2O6S2).6H2O, (II), have structures built upon layers of anions, with the calcium cations and water molecules between these layers. The calcium ions are seven-coordinate. The coordination sphere in compound (I) contains three sulfonate O atoms and four water molecules, while that in (II) contains one sulfonate O atom and six water molecules. Both structures are held together by a network of hydrogen bonds involving the amine, sulfonate and water groups. The biphenyl rings in the anions are approximately 75° out of parallel and the ortho-sulfonate groups are in an anti conformation." @default.
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- W3207595439 date "1996-01-01" @default.
- W3207595439 modified "2023-09-25" @default.
- W3207595439 title "Two Calcium Salts of o-Tolidine-6,6 -disulfonate" @default.
- W3207595439 hasPublicationYear "1996" @default.
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