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- W3207759669 abstract "Immobilizing nanosized electrochemically active materials with supportive carbonaceous framework usually brings in improved lithium-ion storage performance. In this work, magnetite nanoparticles (Fe3O4) are stabilized by both porous carbon domains (PC) and reduced graphene oxide sheets (RGO) to form a hierarchical composite (Fe3O4@PC/RGO) via a straightforward approach. The PC confined iron nanoparticle intermediate sample (Fe@PC) was first fabricated, where sodium carboxymethylcellulose (Na-CMC) was employed not only as a cross-linker to trap ferric ions for synthesizing a Fe-CMC precursor sample, but also as the carbon source for PC domains and iron source for Fe nanoparticles in a pyrolysis process. The final redox reaction between Fe@PC and few-layered graphene oxide (GO) sheets contributed to the formation of Fe3O4 nanoparticles with reduced size, avoiding any severe aggregation or excessive exposure. The Fe3O4@PC/RGO sample delivered a specific capacity of 522.2 mAh·g-1 under a current rate of 1000 mA·g-1 for 650 cycles. The engineered Fe@PC and Fe3O4@PC/RGO samples have good prospects for application in wider fields." @default.
- W3207759669 created "2021-10-25" @default.
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- W3207759669 date "2022-02-01" @default.
- W3207759669 modified "2023-10-16" @default.
- W3207759669 title "Sodium carboxymethylcellulose induced engineering a porous carbon and graphene immobilized magnetite composite for lithium-ion storage" @default.
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- W3207759669 doi "https://doi.org/10.1016/j.jcis.2021.10.068" @default.
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