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- W3207789981 abstract "In the past few decades, palladium-catalyzed cross-coupling reactions have taken root in the construction of a complex synthetic community. The development of organometallics has been an important objective in this field. Our group has focused on exploiting new germanium-based reagents and the corresponding catalytic processes. In the past three years, we have established new methods for the synthesis of structure-modified (hetero)aryl germatranes and alkyl carbagermatranes. Particularly for alkyl carbagermatranes, the stability to be compatible with various derivatization reactions and the high activity for transmetallation (e.g. base/additive-free for primary alkyl carbagermatranes) distinguish them from many reported nucleophiles. In this article, we would introduce (1) the development process of organogermanium reagents in palladium-catalyzed cross-couplings; (2) the history of germatrane-type systems and the breakthrough we have made in the field; (3) the outlook for (carba)germatranes and alkyl-GeMe3." @default.
- W3207789981 created "2021-10-25" @default.
- W3207789981 creator A5066677055 @default.
- W3207789981 creator A5087392457 @default.
- W3207789981 date "2021-01-01" @default.
- W3207789981 modified "2023-10-17" @default.
- W3207789981 title "Germatranes and carbagermatranes: (hetero)aryl and alkyl coupling partners in Pd-catalyzed cross-coupling reactions" @default.
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- W3207789981 doi "https://doi.org/10.1039/d1cc04373k" @default.
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