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- W3207968596 abstract "We present the first enantioselective total synthesis and absolute configuration assignment of (+)-toxicodenane A via a nine-step sequence from the readily available material. The synthesis features a desymmetric enantioselective reduction of 2,2-disubstituted 1,3-cyclohexanedione for the synthesis of a chiral 2,2-disubstituted 3-hydroxy cyclohexanone building block, a highly diastereoselective Grignard reaction for the incorporation of an allyl group, and a Lewis acid-mediated intramolecular transacetalation and Prins cascade reaction for the construction of oxa-bridged bicyclic rings." @default.
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- W3207968596 date "2021-10-15" @default.
- W3207968596 modified "2023-10-18" @default.
- W3207968596 title "Enantioselective Total Synthesis and Absolute Configuration Assignment of (+)-Toxicodenane A" @default.
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- W3207968596 doi "https://doi.org/10.1021/acs.orglett.1c03293" @default.
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