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- W3208124296 abstract "The asymmetric unit of the first title compound iodido(1,4,8,11-tetraazacyclotetradecane-κ 4 N 1 , N 4 , N 8 , N 11 )zinc(II) iodide, [ZnI(C 10 H 24 N 4 )]I, I , consists of the zinc–cyclam macrocyclic cation with one iodide anion coordinated to the metal ion [Zn—I = 2.6619 (5) Å] and the second present as a counter-ion. The asymmetric unit of the second title compound iodido(1,4,8,11-tetraazacyclotetradecane-κ 4 N 1 , N 4 , N 8 , N 11 )zinc(II) triiodide, [ZnI(C 10 H 24 N 4 )]I 3 , II , consists of half of the centrosymmetric macrocyclic cation, in which the Zn II ion coordinated to an iodide anion [Zn—I = 2.766 (2) Å] is disordered over two positions [Zn...Zn = 0.810 (3) Å], and of the two halves of the crystallographically non-equivalent, non-coordinated, centrosymmetric triiodide anions. In both compounds, the N , N , N , N -tetradentate macrocyclic ligand is present in the most energetically favored trans -III conformation. In the crystals of I , the [Zn(C 10 H 24 N 4 )I] + cations and the non-coordinated iodide anions are linked by N—H...I and bifurcated N—H...(I,I) hydrogen bonds, resulting in the formation of two-dimensional networks lying parallel to the (001) and (101) planes. In contrast, the crystals of II are built up from infinite chains of the five-coordinate macrocyclic units arranged along the b -axis direction and perpendicular sheets formed of the triiodide counter-ions without significant hydrogen bonding between them." @default.
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- W3208124296 date "2021-10-29" @default.
- W3208124296 modified "2023-09-30" @default.
- W3208124296 title "Crystal structures of Zn(cyclam)I<sub>2</sub> (second monoclinic polymorph) and Zn(cyclam)I(I<sub>3</sub>)" @default.
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- W3208124296 doi "https://doi.org/10.1107/s2056989021011166" @default.
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