Matches in SemOpenAlex for { <https://semopenalex.org/work/W3208126957> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W3208126957 abstract "Importance of vibronic effects has been highlighted for the singlet-fission (SF) that convert one high-energy singlet exciton into doubled triplet excitons, as strongly correlated multiexcitons. However, molecular mechanisms of spin conversion processes and ultimate de-couplings in the multiexcitons are poorly understood. We have analyzed geometries and exchange couplings of the photoinduced multiexcitons in the pentacene dimers bridged by a phenylene at ortho and meta positions [denoted as <i>o</i>-(Pc)<sub>2</sub> and <i>m</i>-(Pc)<sub>2</sub>] by simulations of the time-resolved electron paramagnetic resonance spectra. We clarified that terahertz molecular conformation dynamics plays a role on the spin conversion from the singlet strongly coupled multiexcitons <sup>1</sup>(TT) to the quintet state <sup>5</sup>(TT). The strongly coupled <sup>5</sup>(TT) multiexcitons are revealed to possess entirely planar conformations stabilized by mutually delocalized spin distributions, while the intramolecular de-coupled spin-correlated triplet pairs generated at 1 microsecond are also stabilized by distorted conformations resulting in two separately localized biradical characters." @default.
- W3208126957 created "2021-11-08" @default.
- W3208126957 creator A5026498329 @default.
- W3208126957 creator A5053677822 @default.
- W3208126957 creator A5075725763 @default.
- W3208126957 creator A5081373673 @default.
- W3208126957 date "2020-08-07" @default.
- W3208126957 modified "2023-09-25" @default.
- W3208126957 title "Geometries and Terahertz Motions Driving Quintet Multiexcitons and Ultimate Triplet-Triplet Dissociations via the Intramolecular Singlet-Fissions" @default.
- W3208126957 doi "https://doi.org/10.26434/chemrxiv.12765002.v1" @default.
- W3208126957 hasPublicationYear "2020" @default.
- W3208126957 type Work @default.
- W3208126957 sameAs 3208126957 @default.
- W3208126957 citedByCount "0" @default.
- W3208126957 crossrefType "posted-content" @default.
- W3208126957 hasAuthorship W3208126957A5026498329 @default.
- W3208126957 hasAuthorship W3208126957A5053677822 @default.
- W3208126957 hasAuthorship W3208126957A5075725763 @default.
- W3208126957 hasAuthorship W3208126957A5081373673 @default.
- W3208126957 hasBestOaLocation W32081269571 @default.
- W3208126957 hasConcept C117633835 @default.
- W3208126957 hasConcept C121332964 @default.
- W3208126957 hasConcept C1276947 @default.
- W3208126957 hasConcept C161522054 @default.
- W3208126957 hasConcept C178790620 @default.
- W3208126957 hasConcept C181500209 @default.
- W3208126957 hasConcept C184779094 @default.
- W3208126957 hasConcept C185592680 @default.
- W3208126957 hasConcept C187961010 @default.
- W3208126957 hasConcept C32909587 @default.
- W3208126957 hasConcept C33062035 @default.
- W3208126957 hasConcept C34742353 @default.
- W3208126957 hasConcept C46141821 @default.
- W3208126957 hasConcept C70050531 @default.
- W3208126957 hasConcept C71240020 @default.
- W3208126957 hasConcept C75079739 @default.
- W3208126957 hasConcept C75473681 @default.
- W3208126957 hasConcept C76766466 @default.
- W3208126957 hasConcept C8010536 @default.
- W3208126957 hasConceptScore W3208126957C117633835 @default.
- W3208126957 hasConceptScore W3208126957C121332964 @default.
- W3208126957 hasConceptScore W3208126957C1276947 @default.
- W3208126957 hasConceptScore W3208126957C161522054 @default.
- W3208126957 hasConceptScore W3208126957C178790620 @default.
- W3208126957 hasConceptScore W3208126957C181500209 @default.
- W3208126957 hasConceptScore W3208126957C184779094 @default.
- W3208126957 hasConceptScore W3208126957C185592680 @default.
- W3208126957 hasConceptScore W3208126957C187961010 @default.
- W3208126957 hasConceptScore W3208126957C32909587 @default.
- W3208126957 hasConceptScore W3208126957C33062035 @default.
- W3208126957 hasConceptScore W3208126957C34742353 @default.
- W3208126957 hasConceptScore W3208126957C46141821 @default.
- W3208126957 hasConceptScore W3208126957C70050531 @default.
- W3208126957 hasConceptScore W3208126957C71240020 @default.
- W3208126957 hasConceptScore W3208126957C75079739 @default.
- W3208126957 hasConceptScore W3208126957C75473681 @default.
- W3208126957 hasConceptScore W3208126957C76766466 @default.
- W3208126957 hasConceptScore W3208126957C8010536 @default.
- W3208126957 hasLocation W32081269571 @default.
- W3208126957 hasLocation W32081269572 @default.
- W3208126957 hasOpenAccess W3208126957 @default.
- W3208126957 hasPrimaryLocation W32081269571 @default.
- W3208126957 hasRelatedWork W18421579 @default.
- W3208126957 hasRelatedWork W19940106 @default.
- W3208126957 hasRelatedWork W24391394 @default.
- W3208126957 hasRelatedWork W25946987 @default.
- W3208126957 hasRelatedWork W26127979 @default.
- W3208126957 hasRelatedWork W26746109 @default.
- W3208126957 hasRelatedWork W34869989 @default.
- W3208126957 hasRelatedWork W3656262 @default.
- W3208126957 hasRelatedWork W5574336 @default.
- W3208126957 hasRelatedWork W9499688 @default.
- W3208126957 isParatext "false" @default.
- W3208126957 isRetracted "false" @default.
- W3208126957 magId "3208126957" @default.
- W3208126957 workType "article" @default.