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• W3208295376 abstract "An efficient sorbent is of great significance in the removal of volatile heavy metal vapors in the municipal solid waste incineration process. In this paper, unlike traditional sorbents based on the formation of silicate, we attempt to develop more effective sorbents by loading phosphate anions on porous montmorillonite (MMT). The adsorption experiments and UV–vis spectrum show that the PbCl2 adsorption capacities of H3PO4@MMT and Na2HPO4@MMT reach the highest values of 0.090 and 0.078 g/g, respectively, when the corresponding loading amounts of phosphate anions are 0.296 and 0.085 g/g, respectively. Compared with traditional sorbents, the adsorption capacity of H3PO4@MMT increases more than 3 times. The analysis of sorbents by Fourier transform infrared (FTIR), X-ray diffraction (XRD), nitrogen adsorption and desorption experiments, and other characterization methods confirm that the loading amount of phosphate anions on H3PO4@MMT is higher than that of Na2HPO4@MMT due to the larger surface area and pore volume formed by the replacement of metal cations with protons from H3PO4. Meanwhile, the prepared sorbent also shows excellent adsorption performance for CoCl2 and NiCl2. Therefore, this study lays a good foundation for the development of new sorbents for the removal of heavy metals during incineration in the future." @default.
• W3208295376 created "2021-11-08" @default.
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• W3208295376 date "2021-11-03" @default.
• W3208295376 modified "2023-09-24" @default.
• W3208295376 title "Improving the Adsorption Capacity of the Sorbent for Gaseous PbCl₂ during Incineration by Forming Pb₃(PO₄)₂: Preparation of the Sorbent and Evaluation of Adsorption Performance" @default.
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• W3208295376 doi "https://doi.org/10.1021/acs.iecr.1c03319" @default.
• W3208295376 hasPublicationYear "2021" @default.
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