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- W3208541211 abstract "Polystyrene and polyvinyl chloride thin films are explored as sample supports for extreme ultraviolet (XUV) spectroscopy of molecular transition metal complexes. Thin polymer films prepared by slip-coating are flat and smooth, and transmit much more XUV light than silicon nitride windows. Analytes can be directly cast onto the polymer surface or co-deposited within it. The M-edge XANES spectra (40-90 eV) of eight archetypal transition metal complexes (M = Mn, Fe, Co, Ni) are presented to demonstrate the versatility of this method. The films are suitable for pump/probe transient absorption spectroscopy, as shown by the excited-state spectra of Fe(bpy)32+ in two different polymer supports." @default.
- W3208541211 created "2021-11-08" @default.
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- W3208541211 date "2021-10-22" @default.
- W3208541211 modified "2023-10-16" @default.
- W3208541211 title "Polymer thin films as universal substrates for extreme ultraviolet absorption spectroscopy of molecular transition metal complexes" @default.
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- W3208541211 doi "https://doi.org/10.1107/s1600577521010596" @default.
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