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- W3208573280 abstract "Abstraction of a pyridine ligand from Weiss' reagent ([PhI(Pyr)2]2+) using BF3-Et2O was found to activate Weiss' reagent towards electrophilic aromatic substitution reactions. The activated species can be isolated when 4-DMAP is used as the pyridine ligand and was determined to be [PhI(4-DMAP)]2+ in solution. The isolated cation was reactive in electrophilic aromatic substitution reactions towards mesitylene, xylene and toluene that Weiss' reagent itself does not react with." @default.
- W3208573280 created "2021-11-08" @default.
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- W3208573280 date "2021-01-01" @default.
- W3208573280 modified "2023-10-17" @default.
- W3208573280 title "Lewis acid activation of Weiss’ reagents ([PhI(Pyr)<sub>2</sub>]<sup>2+</sup>) with boranes and isolation of [PhI(4-DMAP)]<sup>2+</sup>" @default.
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- W3208573280 doi "https://doi.org/10.1039/d1cc04725f" @default.
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