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• W3208579405 endingPage "26573" @default.
• W3208579405 startingPage "26549" @default.
• W3208579405 abstract "Efficient hydrogen storing alternatives are now been pursued for decades. Solid storage systems are currently highly researched due to high volumetric densities at low temperatures and pressure. Still, no developed systems have satisfied even close to the targets given by The United States Department of Energy (DOE) 2020. Although various systems have reported good outputs at nearly room temperatures. The boron-based hydrides (BBHs) are the typical materials. They show a maximum of four reacting B–H bonds and hence have high volumetric densities of hydrogen. The majority of the research has been dealing with dehydrogenation through thermolysis and hydrolysis. This article critically reviews different BBHs for effective hydrogen storage. The first materials reviewed are ammonia borane, lithium borohydride, and sodium borohydride. However, their progress declined in the past few years due to incomplete reactions, elevated dehydrogenation temperature, and purity of hydrogen produced. To overcome these issues, new materials using suitable dopants have been developed since 2000. These materials display enhanced operations along with few drawbacks. Regenerability and numerous other stability factors have been intensively analyzed in this review. Also, different strategies for a system to operate at room conditions have been critically discussed. The findings suggest that BBHs are potential candidates in the field of hydrogen storage, but their applicability highly depends upon the regenerability and recyclability of byproducts." @default.
• W3208579405 created "2021-11-08" @default.
• W3208579405 creator A5005210320 @default.
• W3208579405 date "2022-07-01" @default.
• W3208579405 modified "2023-09-27" @default.
• W3208579405 title "Reversible chemical hydrogen storage in borohydrides via thermolysis and hydrolysis: Recent advances, challenges, and perspectives" @default.
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