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• W3208586907 abstract "Monodisperse polymer brushes were studied by means of Monte Carlo simulations. A coarse-grained model of a polymer brush was designed and the Cooperative Motion Algorithm was employed to model the polymerization process 'grafted from' and to study the structure of a brush immersed in a good solvent. The structure of brushes was determined as a function of the chain length and the grafting density. The influence of these parameters on the scaling properties of the brush was presented and discussed. A thorough analysis of the distribution of concentrations of the polymer segments and the distribution of chain free ends was also carried out. The analysis of the depth of penetration of the low molecular weight solvent into the brush area showed that the main factor determining the penetration is the grafting density. Good agreement between the simulation results and theoretical predictions is observed, especially for longer chains and higher grafting density. The origin of small quantitative differences between the simulation and theoretical results is discussed." @default.
• W3208586907 created "2021-11-08" @default.
• W3208586907 creator A5017659003 @default.
• W3208586907 creator A5041823135 @default.
• W3208586907 date "2021-01-01" @default.
• W3208586907 modified "2023-10-17" @default.
• W3208586907 title "The structure of polymer brushes near the transition from dilute to dense systems. A computer simulation study" @default.
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• W3208586907 doi "https://doi.org/10.1039/d1sm01306h" @default.
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