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• W3208663642 abstract "Rational construction of anode material architecture to afford excellent cycling stability, fast rate capacity, and large specific capacity is essential to promote further development of lithium-ion batteries in commercial applications. In this work, we propose a facile strategy to anchor ultrafine β-Mo2C nanoparticles in N-doped porous carbon skeleton (β-Mo2C@NC) using a scalable salt-template method. The well-defined and abundant hierarchical porous structure of β-Mo2C@NC can not only significantly enhance the electron/ion transfer but also markedly increase the specific surface area to effectively expose the electrochemically accessible active sites. Besides, the N-doped carbon matrix can turn the d-orbital electrons of the Mo to boost the electron transportation as well as distribute active sites to buffer the volume change of Mo2C and provide conductive pathways during discharge/charge cycles. As a result, the as-prepared β-Mo2C@NC displays excellent lithium storage performance in terms of 1701.6 mA h g-1 at 0.1 A g-1 after 100 cycles and a large capacity of 816.47 mA h g-1 at 2.0 A g-1 after 500 cycles. The above results distinctly demonstrate that the β-Mo2C@NC composite has potential application as anode materials in high-performance energy storage devices." @default.
• W3208663642 created "2021-11-08" @default.
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• W3208663642 date "2021-10-30" @default.
• W3208663642 modified "2023-10-18" @default.
• W3208663642 title "Controlled Synthesis of Ultrafine β-Mo₂C Nanoparticles Encapsulated in N-Doped Porous Carbon for Boosting Lithium Storage Kinetics" @default.
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• W3208663642 doi "https://doi.org/10.1021/acsomega.1c03888" @default.
• W3208663642 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8582065" @default.
• W3208663642 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34778632" @default.
• W3208663642 hasPublicationYear "2021" @default.
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